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Using acetone on copper coins - the scientific result is out
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<p>[QUOTE="900fine, post: 215090, member: 6036"]This is not a question of <b>chemistry</b> - it's a question of <b>logic</b>.</p><ol> <li>It doesn't matter what sugars have ketones associated with them, or what the properties of those sugars are. They aren't in play here, so they are irrelevant.</li> <li>Esters are a different class of organic compound. They aren't in play here, so they are irrelevant.</li> <li>We aren't dealing with a ketone GROUP, which I gather in this context is talking about a ketone hanging off some other aliphatic hydrocarbon. They aren't in play here, so they are irrelevant.</li> <li>The only thing which counts is ACETONE and acetone ALONE. It doesn't matter what any other ketones do in any other setting. All that matters is what THIS ketone does in THIS setting - that is, brief contact with metal surfaces followed by a proper rinse with very pure water.</li> <li>The point remains that acetone is <b>relatively</b> inert. It has relatively few reactions :<ol> <li>acid / base catalyzed Hydrolysis : Yes, it can cleave to form acetaldehyde and methanol. But who cares ? Are we introducing acids ? No. Bases ? No.</li> <li>It can be oxidized (burned) : Are we gonna light it up while on the surface of the coin ? I bet we'll get some toning then. <img src="styles/default/xenforo/clear.png" class="mceSmilieSprite mceSmilie104" alt=":yawn:" unselectable="on" unselectable="on" /></li> <li>The big one - acetone is not an oxidizing agent. It does not oxidize the metal surface.</li> </ol></li> </ol><p>Pure acetone is relatively inert - "Relative" meaning compared to other compounds - and only relevant in this numismatic setting.</p><p> </p><p>But the real irony is this : all the chemistry - or "chem-mystery", as some call it - is irrelevant.</p><p> </p><p><b>What really counts is the empirical experience of folks who have tried it with coins.</b></p><p> </p><p>And it's clear it's a terrible idea using cheap-o acetone, and maybe bad all the time. I dunno.</p><p> </p><p>So some real questions are :</p><ol> <li>Has anyone had a GOOD experience, in which the coin never discolored after a long period ? If so, do tell details.</li> <li>When should acetone be used - and when should it be <b>avoided</b> ?</li> <li>Is this considered cleaning ? Does it alter the surfaces ? If so, it is categorically out.</li> <li>Why do dogs have black lips ? (Just seeing if you're still reading...) <img src="styles/default/xenforo/clear.png" class="mceSmilieSprite mceSmilie2" alt=";)" unselectable="on" unselectable="on" /></li> </ol><p>Well, that's the news from Lake Wobegon - where all the men are strong, the women are good-looking, and the coins are above average ![/QUOTE]</p><p><br /></p>
[QUOTE="900fine, post: 215090, member: 6036"]This is not a question of [B]chemistry[/B] - it's a question of [B]logic[/B]. [LIST=1] [*]It doesn't matter what sugars have ketones associated with them, or what the properties of those sugars are. They aren't in play here, so they are irrelevant. [*]Esters are a different class of organic compound. They aren't in play here, so they are irrelevant. [*]We aren't dealing with a ketone GROUP, which I gather in this context is talking about a ketone hanging off some other aliphatic hydrocarbon. They aren't in play here, so they are irrelevant. [*]The only thing which counts is ACETONE and acetone ALONE. It doesn't matter what any other ketones do in any other setting. All that matters is what THIS ketone does in THIS setting - that is, brief contact with metal surfaces followed by a proper rinse with very pure water. [*]The point remains that acetone is [B]relatively[/B] inert. It has relatively few reactions :[LIST=1] [*]acid / base catalyzed Hydrolysis : Yes, it can cleave to form acetaldehyde and methanol. But who cares ? Are we introducing acids ? No. Bases ? No. [*]It can be oxidized (burned) : Are we gonna light it up while on the surface of the coin ? I bet we'll get some toning then. :yawn: [*]The big one - acetone is not an oxidizing agent. It does not oxidize the metal surface.[/LIST][/LIST]Pure acetone is relatively inert - "Relative" meaning compared to other compounds - and only relevant in this numismatic setting. But the real irony is this : all the chemistry - or "chem-mystery", as some call it - is irrelevant. [B]What really counts is the empirical experience of folks who have tried it with coins.[/B] And it's clear it's a terrible idea using cheap-o acetone, and maybe bad all the time. I dunno. So some real questions are : [LIST=1] [*]Has anyone had a GOOD experience, in which the coin never discolored after a long period ? If so, do tell details. [*]When should acetone be used - and when should it be [B]avoided[/B] ? [*]Is this considered cleaning ? Does it alter the surfaces ? If so, it is categorically out. [*]Why do dogs have black lips ? (Just seeing if you're still reading...) ;)[/LIST]Well, that's the news from Lake Wobegon - where all the men are strong, the women are good-looking, and the coins are above average ![/QUOTE]
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Using acetone on copper coins - the scientific result is out
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