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<p>[QUOTE="desertgem, post: 679058, member: 15199"]<a href="http://www.cointalk.com/t60979/" class="internalLink ProxyLink" data-proxy-href="http://www.cointalk.com/t60979/">http://www.cointalk.com/t60979/</a></p><p><br /></p><p>If you read the thread above, you will note the difficulty that Boss had trying to remove a "lacquer" type of coating from a couple of high end Lincolns he had, namely a 1911-d, and a 1916-S. Eventually the thread got to where maybe DMSO might be a possibility, but needed proper handling. I PM-ed Boss and asked if I could see the coins, and he mailed them to me, with permission to try what I felt might work.</p><p><br /></p><p>If you look at the previous thread above, you can see the original photos he had taken.</p><p><br /></p><p>When the coins arrived, I did take the following photos that show the extent of the lacquer. Even though he had used acetone and xylene for extended periods of time, I still tried acetone for 1 hr. looking for any residue, and there was none, so he was correct in it being ineffective. </p><p>I then took these photos of what I now suspected was an acrylic mix.</p><p><br /></p><p><br /></p><p>here is the microscopic photo of the acrylic pooling around the letters on the 16-S </p><p> </p><p> <img src="http://i455.photobucket.com/albums/qq279/desertgem/glazeonrev.jpg" class="bbCodeImage wysiwygImage" alt="" unselectable="on" /></p><p> </p><p><br /></p><p><br /></p><p> <img src="http://i455.photobucket.com/albums/qq279/desertgem/glazerev2.jpg" class="bbCodeImage wysiwygImage" alt="" unselectable="on" /></p><p> </p><p>Before Boss's coins had arrived, I had found some "sacrificial wheaties" with the same level and type of patina, and subjected them to long periods in DMSO, to see if any deleterious change occurred. Even with 24 hrs, after removing, I tried rubbing, plastic scrubbers, toothbrushes, to see if the DMSO had softened the patina that I could damage it. Obviously I wanted no effect, and except for the slight scratches, the patina didn't change level or color, so I asked his permission to try DMSO on the coins.</p><p><br /></p><p>After several changes of DMSO over a 4 hr period, I noticed some residue on the glass containers used, and even took this photo of a </p><p> glob that stuck on the date after the DMSO dissolved most of it.</p><p> <img src="http://i455.photobucket.com/albums/qq279/desertgem/11-d-plasticondate.jpg" class="bbCodeImage wysiwygImage" alt="" unselectable="on" /></p><p> </p><p>But it just flicked off with a sable brush wet with DMSO. Proof for sure there was something on the coin and had been partially removed.</p><p><br /></p><p><br /></p><p> <img src="http://i455.photobucket.com/albums/qq279/desertgem/11-d-plasticpushed.jpg" class="bbCodeImage wysiwygImage" alt="" unselectable="on" /></p><p> </p><p>I finally did not get any more residue, but there was still some "shine" on the coin, and I suspect it is acrylic that is attached so firmly to the metal that physical action would have to be used to remove, and I wasn't going to do that. maybe if it was my coin , I might roll a q-tip over the surface, but not with someone else's. Scratches and wear lines were more apparent after the lacquer was removed, and I assume were the primary reason it was put there in the first place. Here is a photo of the 2 coins as I got ready to return them to Boss. I wished I had taken a photo of the reverses also, but I didn't.</p><p> </p><p> <img src="http://i455.photobucket.com/albums/qq279/desertgem/obverse-final.jpg" class="bbCodeImage wysiwygImage" alt="" unselectable="on" /></p><p> </p><p>and viewed at a light angle to show sheen off obv.</p><p> <img src="http://i455.photobucket.com/albums/qq279/desertgem/obverse-at-angle.jpg" class="bbCodeImage wysiwygImage" alt="" unselectable="on" /></p><p> </p><p>I think the 1911-D will tone up nicely and even with the visible scratch and tiny hairlines will be a nice coin. It appears about AU55 under the scope. The acrylic did hide a lot of problems and probably why done instead of preservation purposes. The 1916-S is AU-58/MS and still has some glossy parts where the acrylic and maybe the dellers interacted a little, but it shouldn't have, so I don't know what made the bluish shiny spots of the rev. of the 16-S. After I mailed them to Boss, I thought maybe the bluish spots is fractured acrylic, producing a fresnel effect, but I am just guessing.</p><p> </p><p> <img src="http://i455.photobucket.com/albums/qq279/desertgem/rev-1.jpg" class="bbCodeImage wysiwygImage" alt="" unselectable="on" /></p><p>Hope I didn't screw anything up, as I think they look more natural now, but it will take some time to see. The thin film of acrylic should eventually degrade. I think they are nice coins myself.</p><p><br /></p><p>DMSO seems to be benign on the patina of copper coins. But I would recommend the clinical/vet type which is 99.9% pure. It is water and alcohol soluble, and I used 91% isopropyl alcohol from Walmart to rinse the DMSO off of the coins and then a final rinse with acetone.</p><p><br /></p><p><img src="http://i455.photobucket.com/albums/qq279/desertgem/IMG_1907.jpg" class="bbCodeImage wysiwygImage" alt="" unselectable="on" /></p><p><br /></p><p>As is the case with all chemical treatment, one should do trials before attempting on special coins. Also the acrylic seems to do a very good job of hiding scratches and tiny pits, so the resulting coin may have more blemishes than previously visible. I thank Boss for giving me the chance to test this procedure.</p><p><br /></p><p><br /></p><p>Jim[/QUOTE]</p><p><br /></p>
[QUOTE="desertgem, post: 679058, member: 15199"][URL]http://www.cointalk.com/t60979/[/URL] If you read the thread above, you will note the difficulty that Boss had trying to remove a "lacquer" type of coating from a couple of high end Lincolns he had, namely a 1911-d, and a 1916-S. Eventually the thread got to where maybe DMSO might be a possibility, but needed proper handling. I PM-ed Boss and asked if I could see the coins, and he mailed them to me, with permission to try what I felt might work. If you look at the previous thread above, you can see the original photos he had taken. When the coins arrived, I did take the following photos that show the extent of the lacquer. Even though he had used acetone and xylene for extended periods of time, I still tried acetone for 1 hr. looking for any residue, and there was none, so he was correct in it being ineffective. I then took these photos of what I now suspected was an acrylic mix. here is the microscopic photo of the acrylic pooling around the letters on the 16-S [IMG]http://i455.photobucket.com/albums/qq279/desertgem/glazeonrev.jpg[/IMG] [IMG]http://i455.photobucket.com/albums/qq279/desertgem/glazerev2.jpg[/IMG] Before Boss's coins had arrived, I had found some "sacrificial wheaties" with the same level and type of patina, and subjected them to long periods in DMSO, to see if any deleterious change occurred. Even with 24 hrs, after removing, I tried rubbing, plastic scrubbers, toothbrushes, to see if the DMSO had softened the patina that I could damage it. Obviously I wanted no effect, and except for the slight scratches, the patina didn't change level or color, so I asked his permission to try DMSO on the coins. After several changes of DMSO over a 4 hr period, I noticed some residue on the glass containers used, and even took this photo of a glob that stuck on the date after the DMSO dissolved most of it. [IMG]http://i455.photobucket.com/albums/qq279/desertgem/11-d-plasticondate.jpg[/IMG] But it just flicked off with a sable brush wet with DMSO. Proof for sure there was something on the coin and had been partially removed. [IMG]http://i455.photobucket.com/albums/qq279/desertgem/11-d-plasticpushed.jpg[/IMG] I finally did not get any more residue, but there was still some "shine" on the coin, and I suspect it is acrylic that is attached so firmly to the metal that physical action would have to be used to remove, and I wasn't going to do that. maybe if it was my coin , I might roll a q-tip over the surface, but not with someone else's. Scratches and wear lines were more apparent after the lacquer was removed, and I assume were the primary reason it was put there in the first place. Here is a photo of the 2 coins as I got ready to return them to Boss. I wished I had taken a photo of the reverses also, but I didn't. [IMG]http://i455.photobucket.com/albums/qq279/desertgem/obverse-final.jpg[/IMG] and viewed at a light angle to show sheen off obv. [IMG]http://i455.photobucket.com/albums/qq279/desertgem/obverse-at-angle.jpg[/IMG] I think the 1911-D will tone up nicely and even with the visible scratch and tiny hairlines will be a nice coin. It appears about AU55 under the scope. The acrylic did hide a lot of problems and probably why done instead of preservation purposes. The 1916-S is AU-58/MS and still has some glossy parts where the acrylic and maybe the dellers interacted a little, but it shouldn't have, so I don't know what made the bluish shiny spots of the rev. of the 16-S. After I mailed them to Boss, I thought maybe the bluish spots is fractured acrylic, producing a fresnel effect, but I am just guessing. [IMG]http://i455.photobucket.com/albums/qq279/desertgem/rev-1.jpg[/IMG] Hope I didn't screw anything up, as I think they look more natural now, but it will take some time to see. The thin film of acrylic should eventually degrade. I think they are nice coins myself. DMSO seems to be benign on the patina of copper coins. But I would recommend the clinical/vet type which is 99.9% pure. It is water and alcohol soluble, and I used 91% isopropyl alcohol from Walmart to rinse the DMSO off of the coins and then a final rinse with acetone. [IMG]http://i455.photobucket.com/albums/qq279/desertgem/IMG_1907.jpg[/IMG] As is the case with all chemical treatment, one should do trials before attempting on special coins. Also the acrylic seems to do a very good job of hiding scratches and tiny pits, so the resulting coin may have more blemishes than previously visible. I thank Boss for giving me the chance to test this procedure. Jim[/QUOTE]
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