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Touching ancient bronze coins with bare hands
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<p>[QUOTE="lrbguy, post: 2825107, member: 88829"]The reaction described in the OP quote does describe the mechanism for bronze disease, but makes a faulty assumption about the bare hand handling of most ancient bronze coins. The chemistry s/he describes assumes that you are touching pure copper or bronze with your bare hands. That is not the case when the coin has a patina. Patina is essentially a non-metallic shell (mainly carbonates and acetates) which forms naturally and shields the elemental copper within from outside contact. It is a conversion of the outer surface of metal into stable non-metallic salts, and these are what protects the coin from destruction while buried in the ground and subject to all kinds of chemical threats. Break through the patina and then bronze disease becomes possible from a number of sources including the transfer of salts by human touch. If your coins have intact patina, you need not fear the threats in the opening paragraph.[/QUOTE]</p><p><br /></p>
[QUOTE="lrbguy, post: 2825107, member: 88829"]The reaction described in the OP quote does describe the mechanism for bronze disease, but makes a faulty assumption about the bare hand handling of most ancient bronze coins. The chemistry s/he describes assumes that you are touching pure copper or bronze with your bare hands. That is not the case when the coin has a patina. Patina is essentially a non-metallic shell (mainly carbonates and acetates) which forms naturally and shields the elemental copper within from outside contact. It is a conversion of the outer surface of metal into stable non-metallic salts, and these are what protects the coin from destruction while buried in the ground and subject to all kinds of chemical threats. Break through the patina and then bronze disease becomes possible from a number of sources including the transfer of salts by human touch. If your coins have intact patina, you need not fear the threats in the opening paragraph.[/QUOTE]
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