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<p>[QUOTE="John Burgess, post: 7666991, member: 105098"]Verdigris and toning are two different things.well not really, but it sounded nice saying it. Hahaha.</p><p>Verdigris is a reaction of copper and water moisture oxygen and contaminants.</p><p>There's a decent write up and progression chart on it here: <a href="https://crescentcitycopper.com/why-does-copper-turn-green/" target="_blank" class="externalLink ProxyLink" data-proxy-href="https://crescentcitycopper.com/why-does-copper-turn-green/" rel="nofollow">https://crescentcitycopper.com/why-does-copper-turn-green/</a></p><p><br /></p><p>Toning, well that's early stage verdigris on copper, verdigris is "terminal toning" of copper. With silver, terminal toning is black, at that point it's a corrosive also it's a silver sulfide. A good chart of toning progression colors all the way to terminal is here: <a href="http://www.jhonecash.com/research/sunnywood_classification.asp" target="_blank" class="externalLink ProxyLink" data-proxy-href="http://www.jhonecash.com/research/sunnywood_classification.asp" rel="nofollow">http://www.jhonecash.com/research/sunnywood_classification.asp</a></p><p><br /></p><p>In either case, copper or silver, toned coins can be pretty and it doesn't hurt anything until it gets to terminal. At that point it becomes a problem as silver sulfide or copper oxide both as a thick layer that includes sulfur, chlorides, and all the stuff that's bad found in air and water in micro particles that have built up over time. It's when it's terminal, whether copper or silver, the toning or patina becomes corrosion and can damage the surfaces and should then be "conserved" to remove this layer that has built up to a thickness that's reached problematic.</p><p><br /></p><p>As far as toning. Some like it, some don't. My opinion, for me it's a natural occurrence of copper or silver, and it's going to happen at some point given enough time and the right environmental conditions. Even if you notice it, it's usually got a really long way to go before it becomes a threat to the coin, and someone that hates toning may dip a coin multiple times and damage the surface trying to keep their coins white when they could have let it ride once it starts and wait for purple/black before conserving. Even then conserving can only be done so many times before it damages the surfaces.</p><p><br /></p><p>It's my understanding that it takes moisture and oxygen for toning to occur, and it take's a carbonate or sulfide to speed it up on its way towards terminal. It's my belief a coin would never tone if it were stored in a container and kept in nitrogen in place of oxygen or in a vacuum let's say, removing the oxygen.</p><p><br /></p><p>I know from pest control, if you have a pest problem, if you remove food or water, or break the life cycle, the pest problem is ended. You remove one of the links so they can't proliferate. I'd think the same applies to toning.</p><p><br /></p><p>What I know is I have 2000s silver proof sets all in their OGP bought from the mint. All have been stored in the same place under the same condition's yet one set has colored up drastically compared to the other 9 sets some are older most are newer. Why? It's got to be a conaminant in the mint packaging of that one set probably a sulfur compound in the packaging.</p><p>What I'm saying is its not random, it's controllable and even possible to retard it. Many have had success with dessicant use to take up the humidity in their storage place, no moisture, no toning.</p><p><br /></p><p>So, at what point does toning become verdigris? "When the toning is terminal" is the simple answer.</p><p><br /></p><p>But it's a complicated question when it's thought about, and I hope I've taken some of the mystery out of it.</p><p><br /></p><p>Disclaimer: I'm a hobbyist not a professional or expert.</p><p><br /></p><p>By the way, Zinc rot isn't actually rot, and also totally controllable it's not a death sentence for a zincoln cent, just like seeing sign of toning isn't a death sentence either.[/QUOTE]</p><p><br /></p>
[QUOTE="John Burgess, post: 7666991, member: 105098"]Verdigris and toning are two different things.well not really, but it sounded nice saying it. Hahaha. Verdigris is a reaction of copper and water moisture oxygen and contaminants. There's a decent write up and progression chart on it here: [URL]https://crescentcitycopper.com/why-does-copper-turn-green/[/URL] Toning, well that's early stage verdigris on copper, verdigris is "terminal toning" of copper. With silver, terminal toning is black, at that point it's a corrosive also it's a silver sulfide. A good chart of toning progression colors all the way to terminal is here: [URL]http://www.jhonecash.com/research/sunnywood_classification.asp[/URL] In either case, copper or silver, toned coins can be pretty and it doesn't hurt anything until it gets to terminal. At that point it becomes a problem as silver sulfide or copper oxide both as a thick layer that includes sulfur, chlorides, and all the stuff that's bad found in air and water in micro particles that have built up over time. It's when it's terminal, whether copper or silver, the toning or patina becomes corrosion and can damage the surfaces and should then be "conserved" to remove this layer that has built up to a thickness that's reached problematic. As far as toning. Some like it, some don't. My opinion, for me it's a natural occurrence of copper or silver, and it's going to happen at some point given enough time and the right environmental conditions. Even if you notice it, it's usually got a really long way to go before it becomes a threat to the coin, and someone that hates toning may dip a coin multiple times and damage the surface trying to keep their coins white when they could have let it ride once it starts and wait for purple/black before conserving. Even then conserving can only be done so many times before it damages the surfaces. It's my understanding that it takes moisture and oxygen for toning to occur, and it take's a carbonate or sulfide to speed it up on its way towards terminal. It's my belief a coin would never tone if it were stored in a container and kept in nitrogen in place of oxygen or in a vacuum let's say, removing the oxygen. I know from pest control, if you have a pest problem, if you remove food or water, or break the life cycle, the pest problem is ended. You remove one of the links so they can't proliferate. I'd think the same applies to toning. What I know is I have 2000s silver proof sets all in their OGP bought from the mint. All have been stored in the same place under the same condition's yet one set has colored up drastically compared to the other 9 sets some are older most are newer. Why? It's got to be a conaminant in the mint packaging of that one set probably a sulfur compound in the packaging. What I'm saying is its not random, it's controllable and even possible to retard it. Many have had success with dessicant use to take up the humidity in their storage place, no moisture, no toning. So, at what point does toning become verdigris? "When the toning is terminal" is the simple answer. But it's a complicated question when it's thought about, and I hope I've taken some of the mystery out of it. Disclaimer: I'm a hobbyist not a professional or expert. By the way, Zinc rot isn't actually rot, and also totally controllable it's not a death sentence for a zincoln cent, just like seeing sign of toning isn't a death sentence either.[/QUOTE]
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