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<p>[QUOTE="dougsmit, post: 2255036, member: 19463"]A few years back I was offered the opportunity to have some of my coins tested for metal by having a tiny hole drilled in the edge. I declined. Proper XRF will require having a spot polished on the edge so the reading would be coin not patina. I'd decline. I do not accept any surface sampling method as valid because we know many coins were struck on flans prepared with acids (on purpose or just as a factor of handling). Surface enrichment and leeching of metals from burial conspire to make the surface different from the core. How significant is this? That would require a study comparing the surface results with fully destructive results on the same specimen. Not on my coins! When someone perfects a method of sampling subsurface composition remotely AND has demonstrated that the results do agree with destructive testing, we might consider it. As it is, I see numbers like 96.1 plus or minus 4.8 troublesome. Warren: As a statistician, can you explain the math here? Disclosure: I did not read the paper.[/QUOTE]</p><p><br /></p>
[QUOTE="dougsmit, post: 2255036, member: 19463"]A few years back I was offered the opportunity to have some of my coins tested for metal by having a tiny hole drilled in the edge. I declined. Proper XRF will require having a spot polished on the edge so the reading would be coin not patina. I'd decline. I do not accept any surface sampling method as valid because we know many coins were struck on flans prepared with acids (on purpose or just as a factor of handling). Surface enrichment and leeching of metals from burial conspire to make the surface different from the core. How significant is this? That would require a study comparing the surface results with fully destructive results on the same specimen. Not on my coins! When someone perfects a method of sampling subsurface composition remotely AND has demonstrated that the results do agree with destructive testing, we might consider it. As it is, I see numbers like 96.1 plus or minus 4.8 troublesome. Warren: As a statistician, can you explain the math here? Disclosure: I did not read the paper.[/QUOTE]
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