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<p>[QUOTE="TIF, post: 2255001, member: 56859"]I read the paper, although not with complete understanding of some passages due to not having read the cited reference papers and not having knowledge of mining and extraction methods.</p><p><br /></p><p>I wonder why their sample size was so tiny? Those Sassanid drachms are available in massive quantities. Maybe they were limited to coins with documented find locations? Still, I'd think there would be considerably more available for nondestructive study. The resulting graph looks pretty but it seems premature to draw conclusions when only one or a few coins per emperor or mint were studied.</p><p><br /></p><p>As for the data's utility in identifying fakes, Doug already mentioned the biggest problem.</p><p><br /></p><p>Kurt-- can you tell me more about the detection depth of XRF? I wonder how accurately it detects a coin's true composition if the coin has been cleaned. For instance, if you clean an Ag-Cu alloy with acid, copper will be removed from the surface, causing the surface to have a higher apparent silver content than the interior ("depletion gilding"). The coins in this study were all soaked in formic acid. I do not know the effect it has on other elements, but it would also lead to a higher apparent percentage of gold at the surface.[/QUOTE]</p><p><br /></p>
[QUOTE="TIF, post: 2255001, member: 56859"]I read the paper, although not with complete understanding of some passages due to not having read the cited reference papers and not having knowledge of mining and extraction methods. I wonder why their sample size was so tiny? Those Sassanid drachms are available in massive quantities. Maybe they were limited to coins with documented find locations? Still, I'd think there would be considerably more available for nondestructive study. The resulting graph looks pretty but it seems premature to draw conclusions when only one or a few coins per emperor or mint were studied. As for the data's utility in identifying fakes, Doug already mentioned the biggest problem. Kurt-- can you tell me more about the detection depth of XRF? I wonder how accurately it detects a coin's true composition if the coin has been cleaned. For instance, if you clean an Ag-Cu alloy with acid, copper will be removed from the surface, causing the surface to have a higher apparent silver content than the interior ("depletion gilding"). The coins in this study were all soaked in formic acid. I do not know the effect it has on other elements, but it would also lead to a higher apparent percentage of gold at the surface.[/QUOTE]
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