It appears to be gunk? Im fairly new to this but i see something different just putting it out there for all you coin pros opinion on what you may see
You know that these are zinc plated iron and any pits that might develop can allow the iron to rust. That's kind of like what it looks like.
Yes, I'm assuming you mean the dark spot. It's either gunk or rust but either way, it's nothing out of the ordinary, just some environmental damage.