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<p>[QUOTE="calcol, post: 4673769, member: 77639"]Doug,</p><p><br /></p><p>If you read the PCGS article on the sniffer, it describes energy-dispersive X-ray spectrometry (EDX) as one of the techniques it uses. EDX is a more generalized term than XRF (x-ray fluorescence). In EDX, atoms of the test material can be excited by any means to emit x-rays, which are analyzed to determine the elements they came from. The two general means of excitation are EMR (electromagnetic radiation), i.e. gamma rays or x-rays ... and x-rays are the usual choice ... OR ... particle bombardment ... electrons in a scanning electron microscope (SEM) are the usual choice. XRF is EDX where the means of exciting the atoms in the test sample is x-rays. Compact XRF units resemble a gun, but some are the size of a car. The larger units can probe more deeply into the sample, focus on smaller areas, and may have automated sample handling as well.</p><p><br /></p><p>The sniffer almost certainly uses an XRF form of EDX. Using a particle accelerator, like a SEM, would be unnecessarily bulky, expensive and technically demanding. Without seeing the innards of the sniffer, it's hard to say how compact its XRF unit is. It may, in fact, be a gun. Many of these have a computer interface.</p><p><br /></p><p>Any stand-alone XRF guns PCGS has are probably used when graders suspect, but aren't certain, that a coin is a counterfeit. If you send a coin to PCGS for elemental analysis, they send it out to a private lab that uses SEM. SEM provides a more accurate elemental analysis. Beyond that, SEM can analyze multiple, very small areas on the coin. An XRF gun is like a shotgun; SEM is like an expensive rifle with a scope.</p><p><br /></p><p>I suggest Wikipedia for further reading:</p><p><br /></p><p><a href="https://en.wikipedia.org/wiki/Energy-dispersive_X-ray_spectroscopy" target="_blank" class="externalLink ProxyLink" data-proxy-href="https://en.wikipedia.org/wiki/Energy-dispersive_X-ray_spectroscopy" rel="nofollow">https://en.wikipedia.org/wiki/Energy-dispersive_X-ray_spectroscopy</a></p><p><br /></p><p><a href="https://en.wikipedia.org/wiki/X-ray_fluorescence" target="_blank" class="externalLink ProxyLink" data-proxy-href="https://en.wikipedia.org/wiki/X-ray_fluorescence" rel="nofollow">https://en.wikipedia.org/wiki/X-ray_fluorescence</a></p><p><br /></p><p>Cal[/QUOTE]</p><p><br /></p>
[QUOTE="calcol, post: 4673769, member: 77639"]Doug, If you read the PCGS article on the sniffer, it describes energy-dispersive X-ray spectrometry (EDX) as one of the techniques it uses. EDX is a more generalized term than XRF (x-ray fluorescence). In EDX, atoms of the test material can be excited by any means to emit x-rays, which are analyzed to determine the elements they came from. The two general means of excitation are EMR (electromagnetic radiation), i.e. gamma rays or x-rays ... and x-rays are the usual choice ... OR ... particle bombardment ... electrons in a scanning electron microscope (SEM) are the usual choice. XRF is EDX where the means of exciting the atoms in the test sample is x-rays. Compact XRF units resemble a gun, but some are the size of a car. The larger units can probe more deeply into the sample, focus on smaller areas, and may have automated sample handling as well. The sniffer almost certainly uses an XRF form of EDX. Using a particle accelerator, like a SEM, would be unnecessarily bulky, expensive and technically demanding. Without seeing the innards of the sniffer, it's hard to say how compact its XRF unit is. It may, in fact, be a gun. Many of these have a computer interface. Any stand-alone XRF guns PCGS has are probably used when graders suspect, but aren't certain, that a coin is a counterfeit. If you send a coin to PCGS for elemental analysis, they send it out to a private lab that uses SEM. SEM provides a more accurate elemental analysis. Beyond that, SEM can analyze multiple, very small areas on the coin. An XRF gun is like a shotgun; SEM is like an expensive rifle with a scope. I suggest Wikipedia for further reading: [URL]https://en.wikipedia.org/wiki/Energy-dispersive_X-ray_spectroscopy[/URL] [URL]https://en.wikipedia.org/wiki/X-ray_fluorescence[/URL] Cal[/QUOTE]
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