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<p>[QUOTE="Oldhoopster, post: 8145721, member: 84179"]<i><b>I would also mention that it is simply a fact that PVC that has the damaging softening agent in it off-gasses, puts of gasses. And this is easily proven to everyone who has ever opened and new PVC shower curtain, or a new pack of flips, and noticed the smell. What you're smelling is that gas. <u>Point being its existence is beyond doubt </u></b></i>(my emphasis)</p><p><br /></p><p>While it appears that Phthalates are major sources of PVC plasticizers, there are others families of plasticizer as well. Could these account for the smell? Could other components contribute to the smell? Do shower curtains and coin flips have the same composition?</p><p><br /></p><p><a href="https://www.polynt.com/plasticizers-for-pvc/" target="_blank" class="externalLink ProxyLink" data-proxy-href="https://www.polynt.com/plasticizers-for-pvc/" rel="nofollow">https://www.polynt.com/plasticizers-for-pvc/</a></p><p><br /></p><p>The point I'm belaboring is that your observations, smells, etc are NOT proof that vapor phase transport of phthalates are a significant mechanism. I posted my observations on using acetone (and Freon 113) to treat an estimated 1000+ raw coins over the last 35 years, and saw no evidence of phthalate vapor phase deposition. Yet I didn't claim that as proof. Why? Because, I didn't have the scientific data to support it. If you believe the credibility of my observations, and the supporting info from [USER=33176]@Kentucky[/USER] great, I'm glad I could help. If you disagree, no problem. I am only providing annectdotal obsevations, NOT PROOF.</p><p><br /></p><p>If you would have said something to the effect that "I've observed xXxX and that may indicate contamination could occur under these conditions", that would have been fine. But to discount other observations because you know your proof is right, doesn't fly, especially in a world of complex chemical reactions, with various components that may change, and difficulty finding appropriate chemical data.</p><p><br /></p><p>Who knows, maybe we do need to worry about plasticizer off gassing. Or maybe we don't. But so far, I see no proof for either and to claim "<i><b>Point being its existence is beyond doubt" </b></i>may be a bit presumptuous[/QUOTE]</p><p><br /></p>
[QUOTE="Oldhoopster, post: 8145721, member: 84179"][I][B]I would also mention that it is simply a fact that PVC that has the damaging softening agent in it off-gasses, puts of gasses. And this is easily proven to everyone who has ever opened and new PVC shower curtain, or a new pack of flips, and noticed the smell. What you're smelling is that gas. [U]Point being its existence is beyond doubt [/U][/B][/I](my emphasis) While it appears that Phthalates are major sources of PVC plasticizers, there are others families of plasticizer as well. Could these account for the smell? Could other components contribute to the smell? Do shower curtains and coin flips have the same composition? [URL]https://www.polynt.com/plasticizers-for-pvc/[/URL] The point I'm belaboring is that your observations, smells, etc are NOT proof that vapor phase transport of phthalates are a significant mechanism. I posted my observations on using acetone (and Freon 113) to treat an estimated 1000+ raw coins over the last 35 years, and saw no evidence of phthalate vapor phase deposition. Yet I didn't claim that as proof. Why? Because, I didn't have the scientific data to support it. If you believe the credibility of my observations, and the supporting info from [USER=33176]@Kentucky[/USER] great, I'm glad I could help. If you disagree, no problem. I am only providing annectdotal obsevations, NOT PROOF. If you would have said something to the effect that "I've observed xXxX and that may indicate contamination could occur under these conditions", that would have been fine. But to discount other observations because you know your proof is right, doesn't fly, especially in a world of complex chemical reactions, with various components that may change, and difficulty finding appropriate chemical data. Who knows, maybe we do need to worry about plasticizer off gassing. Or maybe we don't. But so far, I see no proof for either and to claim "[I][B]Point being its existence is beyond doubt" [/B][/I]may be a bit presumptuous[/QUOTE]
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