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<p>[QUOTE="JMGallego, post: 2666363, member: 35622"]Hi [USER=15199]@desertgem[/USER],</p><p><br /></p><p>Yes, several scientific articles describing the bonding and structure of the CuBTA. One of this article published back in 1989 entitled "COORDINATION POLYMERIZATION OF BENZOTRIAZOLE ON THE SURFACE OF METALLIC COPPER". In this article, the authors explain the chemistry and explain the film composition. They conclude: "We have shown that BTAH can react with copper metal other than copper cations or oxides in extremely mild conditions. The reaction product is mainly bis ( benzotriazolato ) copper ( II ), which covers the surface in the shape of a polymeric material." They used infrared (middle) and X- ray photoelectron spectroscopies and elemental analysis.</p><p><br /></p><p>Another interesting one is the 2009 article "A review of the effects of benzotriazole on the corrosion of copper and copper alloys in clean and polluted environments". In it, it has a section called "Benzotriazole: its chemistry and mode of action" that explains in detail the how the bond is created. Another section is the "Inhibiting effects of benzotriazole, its derivatives, and blends". Very interesting article.</p><p><br /></p><p>And there are plenty of articles on analyzing BTA film on the surface of copper. Just to mention a couple, one is the 1970 "Reflection infra-red studies of films formed by benzotriazole on Cu", the 1990 "The use of near-infrared Fourier Transform techniques in the study of surface enhanced Raman spectra" and the 1985 "A photoemission study of the adsorption of benzotriazole on copper"</p><p><br /></p><p>These are just a few articles, there are many more and recent ones.[/QUOTE]</p><p><br /></p>
[QUOTE="JMGallego, post: 2666363, member: 35622"]Hi [USER=15199]@desertgem[/USER], Yes, several scientific articles describing the bonding and structure of the CuBTA. One of this article published back in 1989 entitled "COORDINATION POLYMERIZATION OF BENZOTRIAZOLE ON THE SURFACE OF METALLIC COPPER". In this article, the authors explain the chemistry and explain the film composition. They conclude: "We have shown that BTAH can react with copper metal other than copper cations or oxides in extremely mild conditions. The reaction product is mainly bis ( benzotriazolato ) copper ( II ), which covers the surface in the shape of a polymeric material." They used infrared (middle) and X- ray photoelectron spectroscopies and elemental analysis. Another interesting one is the 2009 article "A review of the effects of benzotriazole on the corrosion of copper and copper alloys in clean and polluted environments". In it, it has a section called "Benzotriazole: its chemistry and mode of action" that explains in detail the how the bond is created. Another section is the "Inhibiting effects of benzotriazole, its derivatives, and blends". Very interesting article. And there are plenty of articles on analyzing BTA film on the surface of copper. Just to mention a couple, one is the 1970 "Reflection infra-red studies of films formed by benzotriazole on Cu", the 1990 "The use of near-infrared Fourier Transform techniques in the study of surface enhanced Raman spectra" and the 1985 "A photoemission study of the adsorption of benzotriazole on copper" These are just a few articles, there are many more and recent ones.[/QUOTE]
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