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Issue with a 1964 Presidential Coin Set
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<p>[QUOTE="Oldhoopster, post: 2732726, member: 84179"]No idea if this is correct, but here is a possible explanation on why the coin has the black level of dark toning for over 50 years. Toning is caused by the silver atoms on the surface of the coin reacting to other elements such as oxygen and particularly sulfur (simplified explanation). The speed of the reaction will depend on the environment and concentration of the contaminant. As the sulfide layer gets thicker the color will turn darker. Over time, there is less “fresh” silver left to react and it takes longer for the sulfur to penetrate through the toning layer. At some point, the toning will slow as the coin darkens. </p><p><br /></p><p><br /></p><p>If the coin was exposed to a highly concentrated sulfur environment as it sat at the end of a coin roll, the exposed surfaces could tone very rapidly. Once removed from this environment and placed in the display, toning would slow. The newly exposed fresh surfaces would tone over time, but the dark area, with the thick sulfide layer would not appear to get much darker.</p><p><br /></p><p><br /></p><p>Once again, it’s unlikely that the actual cause can be determined but it’s interesting to speculate and I think this explanation may be a good possibility.[/QUOTE]</p><p><br /></p>
[QUOTE="Oldhoopster, post: 2732726, member: 84179"]No idea if this is correct, but here is a possible explanation on why the coin has the black level of dark toning for over 50 years. Toning is caused by the silver atoms on the surface of the coin reacting to other elements such as oxygen and particularly sulfur (simplified explanation). The speed of the reaction will depend on the environment and concentration of the contaminant. As the sulfide layer gets thicker the color will turn darker. Over time, there is less “fresh” silver left to react and it takes longer for the sulfur to penetrate through the toning layer. At some point, the toning will slow as the coin darkens. If the coin was exposed to a highly concentrated sulfur environment as it sat at the end of a coin roll, the exposed surfaces could tone very rapidly. Once removed from this environment and placed in the display, toning would slow. The newly exposed fresh surfaces would tone over time, but the dark area, with the thick sulfide layer would not appear to get much darker. Once again, it’s unlikely that the actual cause can be determined but it’s interesting to speculate and I think this explanation may be a good possibility.[/QUOTE]
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