How old is @BadThad, the chemist? How long has he been a professional numismatist as that may explain things. Say something long enough and change happens. Anyway, the Internet appears to agree with his definition at the moment as I have more research to do.
I am sure he is much younger than either you or I. I would also venture he has been a "professional numismatist" ( studies coins and has made a name and money from his efforts) longer than you have been a professional chemist. I am curious why you found it necessary to bring his name in here. I think everyone should slow down the argumentative mode before someone has deep regrets, and think before giffing or posting. Thanks. Jim
One of the members @ him! @ comments on dipping and cleaning threads and developed Verti-Care (but you know all that - right?). We are having a discussion and it seems that the usage/meaning of certain descriptive adjectives has changed from the way they were used when I learned about the surface characteristics of coins in the past. I'm curious to know when this happened. That's why the age of @ matters. The change either took place before or after he came of age. The fact that he actually is a young professional numismatist who makes a living with coins lends more weight to his opinions as he may have helped change long held definitions of patina and verdigris. Change is inevitable. Long ago coins were called "double dies." Decades ago the correct term "doubled die" replaced it. I already mentioned in the 1970's that the ANA taught "whizzing" was chemical cleaning. So now, I want to research the "change" that has taken place to "verdigris." @ may know something...that's all.
Thad posted twice in this thread and only used the word verdigris in one, just saying he saw little of it in the sample from a friend, nothing descriptive at all. We do have PM that can be used to directly ask questions (but you know all that - right?). Age has little to do with ones knowledge and profession. You can start a new thread on word definitions if you wish to research further, but lets try to keep it amiable. One or a couple of visuals such as gifs can enhance the emotion of a post, but excessive overuse can be an indication of aggressive posting, which I am sure is not your true desire. Thanks .
In the past we've had some good discussions regarding these words - verdigris, patina, bronze disease. Depending on who you talk to each of those words can be used to describe entirely different things, or the exact same thing. And each of them can have a negative or a positive connotation, again depending on who you talk to - and the context in which they are being used. We've got 3 people here that I know of who are chemists - Kentucky, desertgem, and BadThad. We may have more, but I know of those 3. They'll use terms like oxide, and chloride, sulfate, sulfide, and and and. And to them they know exactly what they are talking about and their differences or similarities, while we laymen often do not. To a lot of us, it's all just green stuff, that's the group I'm in - it's green stuff. Patina is a little different in that it is can be used, and accurately so, to describe many different colors, not just green. And sometimes, even when the patina is green, it's still different, or thought to be different anyway. But verdigris and bronze disease, to the best of my knowledge they're pretty much always green. But the one thing that all 3 of these, patina, verdigris, and bronze disease, have in common is that they are, simply put, corrosion, or the result of corrosion. At least as I understand it. I mean when you come right down to it, even though we (coin collectors, numismatists) don't refer to it as such, toning is nothing more than corrosion. It is the effect of the elements on metal. And those elements can come into contact with coins in many different ways, direct contact in liquid form, the ground, the very air we breathe. There's just no way to avoid it, all metal comes into contact with the elements in one way or another. And corrosion is the result. But we don't always like to call it corrosion. Corrosion has too much of a negative connotation. So we'll use words like patina, or toning because they, well they just sound better. They can have or at least lend a "positive" aspect instead of a "negative" aspect to the things we care about, the things we like. In other words they are euphemisms. And that's why bronze disease and/or verdigris is sometimes referred to as patina. I mean verdigris just doesn't sound good, and bronze disease, well how could anything that is a "disease" possibly be good ? But when ancient collectors are talking about their coins and the verdigris that has formed on them over the centuries has become hard, a solid surface almost, they refer to it as patina. Why ? Well I think it's because it just sounds better. It's no different than the rest of us calling corrosion on our coins toning - that just sounds better. It makes us feel better about the things that we like, the things we care about. But when push comes to shove - it's all just corrosion. Patina, toning, verdigris, bronze disease - it's all just corrosion. The chemical compositions may be different, but it's all still just the same thing. It's no different than calling cleaning conservation - they're both the exact same thing, but one sounds better than the other. And we do that with all sorts of words, we choose to use words when describing our coins that make us feel better about them. And if the definition of that word doesn't really fit well then we just kind of change that defintion to suit our own purposes at the time. Over time and with continued use before ya know it one thing means something else because people are willing to accept things that make them feel better, things that change a negative to a positive.
I'm no chemist. I am going to change my terminology based on posts in this thread and some recent Internet research. I've learned that Verdigris is a "hard" encrustation of various chemical compositions in shades of blue and green that forms on copper or brass due to oxidation. It is also called "patina." So from now on, when I see the soft, green crud forming on the surface of copper (see Post#280) I will just call it "crud" This appears to be one more case where the old teachings were incorrect and the younger, more informed numismatists corrected the record. Thanks for the education
Not always, it is very often a soft, flaky substance that you can almost blow off the coin. Heck sometimes pieces of it can fall off the coin all by itself just from picking the coin up. But yeah, other times it can become hard, but only under certain circumstances. The presence of moisture, pressure, other chemicals in the air or ground, one or all of these things can cause what was originally soft and flaky to become hard and crusty over time.
Isn't corrosion describing the effect, and patina is the layer and color that forms? And, maybe verdigris is a type of patina - one that easily falls off. The dictionary definitions use "patina" in its description of verdigris. So, isn't verdigris a layer that forms that easily falls off, whereas toning has a stronger bond? ------ Doesn't that mean they are types of, from more general to more specific: Corrosion > Patina > Verdigris & Toning The above would be easier to see in a "tree-branch" diagram. Is the above correct, below the dashed lines?
Only if you're someone who uses those terms that way. These are among the most ill-defined words in numismatics. If you like the coin, it's patina and toning. If you don't, it's verdigris and corrosion.
I'll take a stab on this based on my new understanding. Isn't corrosion describing the effect, and patina is the layer and color that forms? Corrosion, patina, verdigris, toning, etc. are all physical manifestations of oxidation. All of the above characteristics can be said to affect the surface (raised or into). However, they are usually regarded differently. Patina is often used to describe "pretty" corrosion. Just as tarnish is used to describe "ugly" toning. And, maybe verdigris is a type of patina - one that easily falls off. Apparently, verdigris is just another word for a similar product of oxidation. A quick look on the Internet shows objects with pretty verdigris and some that are just plain corrosion! The dictionary definitions use "patina" in its description of verdigris. True, the two words seem to be interchangeable. Nevertheless, I think "patina" conjures up something more "favorable." So, isn't verdigris a layer that forms that easily falls off, whereas toning has a stronger bond? IMO, toning is a strong bond; however some forms of toning (color) will wipe off a surface. Patina or verdigris is also a strong bond as the metal is being destroyed at the point of contact. The fact that it can be powder-like on its top surface is just like more familiar rust. The metal has "brown colored rust (patina)" and in many cases the top layer can be rubbed off like a powder. NOW, patina or verdigris should not be used to describe a brown surface (as my example) as it refers to green and blue coloration. Sorry to add this: Right or wrong - glossy brown ancient coins have been described as having "patina." ------ Doesn't that mean they are types of, from more general to more specific: Corrosion > Patina > Verdigris & Toning The above would be easier to see in a "tree-branch" diagram. Is the above correct, below the dashed lines? I think rather than a progression they are technically all the same thing. If there are no misstatements here, I think I finally "get it."