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<p>[QUOTE="Lehigh96, post: 1000117, member: 15309"]I can only help a little as I have not worked in the metallurgical field for many years. The need to anneal silver prior to the coining process is actually caused by earlier processes within the coining process. In order to make the planchets, the silver must be rolled in order to get the sheet of metal to the desired thickness before the planchets can be punched. This rolling process is a form of cold working which has the effect of increasing hardness while simultaneously decreasing ductility. The annealing stage allows for the softening of the metal by raising the temperature of the metal to the point that it recrystallizes. Once this is done and the metal is air cooled, it will be sufficiently ductile for the coin process.</p><p><br /></p><p>Now here is where my absence from the metallurgical field hurts me. Most of my experience with annealing was applicable to engineering metals such as steel and aluminum. I have very little experience with precious metals such as silver. However, I do know that controlling the annealing process is important with all metals and the greater measure of control with regards to time and temperature will yield better results. In that regard, I must assume that the gas furnaces were capable of producing a much more consistent product.</p><p><br /></p><p>Having said all that, I am not sure if the annealing process has anything at all to do with the corrosion of the metal. Martensitic steel will corrode just as easily as ferritic steel, or even pearlitic steel. Given that knowledge, I don't know what effect (if any) the annealing process would have on the corrosion process of silver. The crystalline lattice structure of silver is FCC (Face Centered Cubic). Annealing affects the mechanical properties of the metal (ductility & hardness) by changing grain size and orientation but the crystal structure remains unchanged. The effect of grain size on the corrosion of silver is beyond the scope of my metallurgical background.[/QUOTE]</p><p><br /></p>
[QUOTE="Lehigh96, post: 1000117, member: 15309"]I can only help a little as I have not worked in the metallurgical field for many years. The need to anneal silver prior to the coining process is actually caused by earlier processes within the coining process. In order to make the planchets, the silver must be rolled in order to get the sheet of metal to the desired thickness before the planchets can be punched. This rolling process is a form of cold working which has the effect of increasing hardness while simultaneously decreasing ductility. The annealing stage allows for the softening of the metal by raising the temperature of the metal to the point that it recrystallizes. Once this is done and the metal is air cooled, it will be sufficiently ductile for the coin process. Now here is where my absence from the metallurgical field hurts me. Most of my experience with annealing was applicable to engineering metals such as steel and aluminum. I have very little experience with precious metals such as silver. However, I do know that controlling the annealing process is important with all metals and the greater measure of control with regards to time and temperature will yield better results. In that regard, I must assume that the gas furnaces were capable of producing a much more consistent product. Having said all that, I am not sure if the annealing process has anything at all to do with the corrosion of the metal. Martensitic steel will corrode just as easily as ferritic steel, or even pearlitic steel. Given that knowledge, I don't know what effect (if any) the annealing process would have on the corrosion process of silver. The crystalline lattice structure of silver is FCC (Face Centered Cubic). Annealing affects the mechanical properties of the metal (ductility & hardness) by changing grain size and orientation but the crystal structure remains unchanged. The effect of grain size on the corrosion of silver is beyond the scope of my metallurgical background.[/QUOTE]
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