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<p>[QUOTE="frech001, post: 2991285, member: 20616"]I had a couple of otherwise nice coppers in my collection that had one or two black spots on them that bothered me enough to experiment. I've done a bit of plumbing on copper pipes and had some zinc chloride solder flux. I used a fine tipped artist's brush to apply a tiny drop of Zinc Chloride (available as liquid solder flux at hardware stores) to the black spots. It quickly dissolves copper oxidation, green oxidation and black sulfur spots. Wash off within a minute or less with warm water and carefully dry the coin with a soft cotton cloth without rubbing, just blotting it dry. There may be a spot of lighter copper exposed that can be blended in with mixture of powdered sulfur and mineral oil. But quickly remove this as soon as the color blends with the surrounding patina. Rinse the coin in acetone to remove remaining oils and handle with gloves. Try this on some junk coins before you try it on one in your collection. As another poster noted, if the oxidation is deeper than the surface, the zinc chloride will leave a noticeable depression where the oxidation had been. It does not seem to attack the copper, just removes oxidation but it stops the progress of copper "rust" or bronze disease. I haven't tried baking soda and distilled water, but apparently that can be used also for bronze disease - green verdigris, but takes longer and the coin is soaked in the solution for an hour or more. Google search "How to Remove Verdigris From Coins” (with the quotes).[/QUOTE]</p><p><br /></p>
[QUOTE="frech001, post: 2991285, member: 20616"]I had a couple of otherwise nice coppers in my collection that had one or two black spots on them that bothered me enough to experiment. I've done a bit of plumbing on copper pipes and had some zinc chloride solder flux. I used a fine tipped artist's brush to apply a tiny drop of Zinc Chloride (available as liquid solder flux at hardware stores) to the black spots. It quickly dissolves copper oxidation, green oxidation and black sulfur spots. Wash off within a minute or less with warm water and carefully dry the coin with a soft cotton cloth without rubbing, just blotting it dry. There may be a spot of lighter copper exposed that can be blended in with mixture of powdered sulfur and mineral oil. But quickly remove this as soon as the color blends with the surrounding patina. Rinse the coin in acetone to remove remaining oils and handle with gloves. Try this on some junk coins before you try it on one in your collection. As another poster noted, if the oxidation is deeper than the surface, the zinc chloride will leave a noticeable depression where the oxidation had been. It does not seem to attack the copper, just removes oxidation but it stops the progress of copper "rust" or bronze disease. I haven't tried baking soda and distilled water, but apparently that can be used also for bronze disease - green verdigris, but takes longer and the coin is soaked in the solution for an hour or more. Google search "How to Remove Verdigris From Coins” (with the quotes).[/QUOTE]
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