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<p>[QUOTE="Kentucky, post: 1772474, member: 33176"]Actually I did not say what you said. I said that a layer of silver oxide or a layer of silver sulfide would give the same appearance depending on the thickness of the layer. The color is caused by reflection/refraction of light that can be interfered with constructively or destructively depending on the thickness of the film. Why do soap bubbles show some of the rainbow toning we see on some silver coins? The soap material is white or transparent, so the color here is a similar phenomenon. Now, if we go further, either process of forming silver sulfide of silver oxide is an oxidation of the silver. If the silver oxide gets thicker, the coin will dull and be kind of lusterless, while if the silver sulfide gets thicker, we have more of a chance of the coin turning black as in classical tarnish. I try not to get too dogmatic about chemical stuff because guys that have been around coins as much as someone like Doug have actually seen a bunch of stuff it would be very hard for me to intelectuallize. It's like trying to instruct a chem lab using a manual where a very knowledgeable chemist has written the experiments, but obviously hasn't done them because in practice, lots of thing are quite different than theory. I don't know anything about the Coin Armour having never used it and haven't read the literature.[/QUOTE]</p><p><br /></p>
[QUOTE="Kentucky, post: 1772474, member: 33176"]Actually I did not say what you said. I said that a layer of silver oxide or a layer of silver sulfide would give the same appearance depending on the thickness of the layer. The color is caused by reflection/refraction of light that can be interfered with constructively or destructively depending on the thickness of the film. Why do soap bubbles show some of the rainbow toning we see on some silver coins? The soap material is white or transparent, so the color here is a similar phenomenon. Now, if we go further, either process of forming silver sulfide of silver oxide is an oxidation of the silver. If the silver oxide gets thicker, the coin will dull and be kind of lusterless, while if the silver sulfide gets thicker, we have more of a chance of the coin turning black as in classical tarnish. I try not to get too dogmatic about chemical stuff because guys that have been around coins as much as someone like Doug have actually seen a bunch of stuff it would be very hard for me to intelectuallize. It's like trying to instruct a chem lab using a manual where a very knowledgeable chemist has written the experiments, but obviously hasn't done them because in practice, lots of thing are quite different than theory. I don't know anything about the Coin Armour having never used it and haven't read the literature.[/QUOTE]
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