Coin experiment gives surprising results!

Discussion in 'Coin Chat' started by Spark1951, Jan 27, 2018.

  1. Spark1951

    Spark1951 Accomplishment, not Activity

    Reverse electroplating a 1982-D copper LMC. I found this experiment on Pinterest, if anyone wants to go find it for themselves.

    It involves finding an old device wall transformer and crimping alligator clips to the ends. You immerse an old stainless steel spoon in a solution of CITRIC acid diluted with water and connect the positive clip to the spoon. I used 8 oz. tap water with the juice of 1/2 lemon as my solution. The negative clip attaches to the coin under test.

    Once immersed, you need to ensure the spoon and coin remain apart, then plug in the transformer into your wall outlet. My transformer output was 16 volts direct current (vdc) and was strong enough. 12 vdc is good too, weaker and you must run the test longer. There are pitfalls, but worth it if you are careful as you will see by my results.

    My original coin, lots of corrosion. The experiment is supposed to remove all non-metallic debris.
    image.jpg
    The coin will begin to fizz within a few seconds of plugging in the transformer, but the wires don't get hot or even warm. You must be careful attaching the clip to the coin to avoid adding contact marks. Here is after 30 minutes:
    image.jpg
    Next, after a total of one hour:
    image.jpg
    Next, 3 hours. Notice the halo effect where the clip was attached:
    image.jpg
    Final result after a light swab with acetone:
    image.jpg
    Honest...same coin. Acetone removed debris from the test including the halo. The only negatives were an additional new contact mark from the clip and the fact that it is now a cleaned coin. This coin was a sacrificial lamb to test the procedure, obviously it was not a "keeper". I will keep it as a specimen.
    Comments?
     
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  3. afantiques

    afantiques Well-Known Member

    By removing the outermost copper atoms you also remove the corrosion that is chemically attached to them.
     
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  4. lordmarcovan

    lordmarcovan Eclectic & Eccentric Moderator

    Nice result.

    This is electrolysis. I found it handy in the past, using a similar method to clean my detecting finds. As you hinted, there are pitfalls, though.

    You'll want to wanna watch out you don't overdo it. I accidentally "burnt up" the first large cent I ever found. It was heavily corroded, though I could tell it was a 1796-1807 Draped Bust cent. Because it had unstable surfaces (it had been in the ground near the edge of a salt marsh), I ended up with nothing but a featureless slug after attempting electrolysis.

    (When first dug, you could barely see Lady Liberty's hair bow and a wreath on the coin- just enough to ID the type. By trying to coax a date off the coin, though, and using electrolysis process, I ruined it. Not that it was in really great shape to begin with.)

    I will say that this electrolysis process worked great on silver, though, and sometimes on dark nickels.

    Just proceed with caution on really porous or corroded stuff- you can make it worse, as I did. But generally speaking, this process can be a useful tool.
     
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  5. Spark1951

    Spark1951 Accomplishment, not Activity

    While in progress I had my reservations of effectiveness. I was amazed at the result.
     
  6. MontCollector

    MontCollector Well-Known Member

    I like the results.

    Can you make something that makes contact with the coin and still conduct electricity, but doesn't leave marks?
     
  7. Spark1951

    Spark1951 Accomplishment, not Activity

    The focus of the Pinterest article was to salvage coins found while metal detecting. Said it was used on some extremely damaged, buried coins, so, in this instance a useful tool to recover an otherwise unwanted, irredeemable coin that had been in the ground for decades, if not centuries.
     
  8. Spark1951

    Spark1951 Accomplishment, not Activity

    You might put a flattenned piece of metal on either side of the coin to avoid the bite of the clip. But it would have to be copper as well to avoid dissimilar metals. Or you would have to find a specialized copper clip of some kind.
     
  9. lordmarcovan

    lordmarcovan Eclectic & Eccentric Moderator

    Yes, that is exactly what I used it for. But when your unwanted, irredeemable coin happens to be something like a 200-year-old Draped Bust cent you're trying to retrieve a date from (even though it will never be worth much money), you should proceed cautiously, is all I'm sayin'.

    (My find could very well have been a 1799 cent, which even in the most horrendous condition would've been worthwhile, for instance.)
     
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  10. Spark1951

    Spark1951 Accomplishment, not Activity

    Just hit me...what if this coin had been a small date copper.....
     
  11. lordmarcovan

    lordmarcovan Eclectic & Eccentric Moderator

    Then it still would have been a Memorial cent with surface issues. LOL ;)

    (Sorry, those personally do nothing at all for me. LMC are not on my radar at all, though now that they're technically obsolete, I suppose they shall have their day eventually.)
     
  12. Spark1951

    Spark1951 Accomplishment, not Activity

    ....and I take your advice seriously. I will proceed with caution...I have plenty of "test subjects".
     
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  13. daveydempsey

    daveydempsey Well-Known Member

    Old phone chargers are best for this, I also add a little salt solution.
    I`ve actually had mine for around ten years, lots of examples on YouTube.
     
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  14. ldhair

    ldhair Clean Supporter

    Most transformers/chargers will show the output. The voltage is not as important as the amperage. Phone chargers work well because of the low amperage. Higher amperage ones can cook a coin.
     
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  15. V. Kurt Bellman

    V. Kurt Bellman Yes, I'm blunt! Get over your "feeeeelings".

    It's like elfen magic.
     
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  16. -jeffB

    -jeffB Greshams LEO Supporter

    The limiting factor would probably be the resistance of the solution, and that's determined by its concentration (how much citric acid you put in) and the size and composition of the electrodes (coin and whatever you use on the other side).

    If a charger says "5 volts, 2 amps", that means it'll provide 5 volts at up to 2 amps. Most likely, you'll draw nowhere near 2 amps, though, unless you touch the electrodes together (short-circuit). If you try to draw more than 2 amps, either the output voltage will drop, the charger will cut itself off, or it'll overheat and fail.

    A higher-voltage charger will push more current through the same resistance. In other words, if a 5-volt charger pushes 0.5 amp through your setup, a 12-volt charger would push 1.2 amp (as long as everything is arranged exactly the same).

    I really, really should experiment with this myself -- I've got a couple of power supplies that let me set the current, and then provide whatever voltage is needed to drive exactly that much current.
     
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  17. Colonialjohn

    Colonialjohn Active Member

    This form of silver electrodeposition or your explanation of electrolysis is explained in my new book "Forgotten Coins." There amay be hundred's? of Mexican Cap and Rays Eight Reales which are counterfeited as the direct result of silver electrodeposition or silver electrolysis. This advanced form of counterfeiting replaces the Sheffield Plate types that we discussed in Gurney's Eight Reale counterfeit book. We are currently looking deeper into these C&R 8R's in this post-1840 counterfeiting method. See this link - an entire chapter discusses this new form of counterfeit in raw and found in slabs:

    https://www.amazon.com/Forgotten-Co.../ref=tmm_kin_swatch_0?_encoding=UTF8&qid=&sr=
     
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  18. Roman Collector

    Roman Collector Well-Known Member

    Water softener (sodium sesquicarbonate) is safer for your coins than citric acid. You can even spare a patina if you are careful. This was the method used to clean the Bath Hoard:

    Scan.jpeg
    beau-Street-Hoard.jpg
    Use about 2-3 teaspoons in 8 ounces of warm, distilled water. It takes a few to several minutes to remove the corrosion. Watch the coin closely.

    Wash the coin with soap and water when you're done, then rinse in distilled water and let it dry naturally.
     
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  19. David Setree Rare Coins

    David Setree Rare Coins Well-Known Member

    None the less.....


    Looks cleaned to me.
     
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  20. Spark1951

    Spark1951 Accomplishment, not Activity

    Seasoned coin folk agree that my final result does indeed look like it's been cleaned, because it has been. However on a scale of 0 to 10, the original condition was a 0, and the salvaged result maybe a 2.
    On a consistant basis, at least since 1962, I stay away from coins that need to be cleaned and am discouraged when I find one. And sometimes it happens the hard way.

    I inherited a beautiful Peace dollar from my Mom back on 2007. It had a proof-like finish and I thought it was MS65. It came back from ANACS "AU58 Details"...they determined it had been polished, another form of cleaning or altering coins.

    I remain a staunch supporter of non-altered coins, but sometimes you run across one you just gotta get the grime off of.
     
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  21. lordmarcovan

    lordmarcovan Eclectic & Eccentric Moderator

    Oh, despite the fact that the coin you treated started out being worth one cent and ended up being worth one cent, I'd say from an aesthetic standpoint you improved it considerably. I was impressed with the final result.
     
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