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<p>[QUOTE="desertgem, post: 761932, member: 15199"]In relation to gold toning. The color of gold is determined by relativistic effects. Metals such as silver absorb and reflect photons of color energy due to an "electron sea" on their surface. Gold would also be a silver color except for this relativistic effect. Gold absorbs a "blue" energy photon and reflects the "redder" energy photon as an internal electron moves from the 5d to 6s orbit. Gold atom shifts the frequency enough to put the photon in the visible color range while a silver atom does not. This color of gold can vary as any surrounding atoms of non-gold alters their composition through oxidation. Gold itself does NOT form a stable oxide below thousands of atmospheres of pressure oxygen, so any color change of gold occurs because of the internal energy relationships of the atomic shells of the atom. </p><p><br /></p><p>There are quantum aspects as to velocity of electrons in more electropositive nuclei such as gold ( color ) compared to silver ( basically colorless), but the better physicists can probably work through that. Copper also has a color due to similar reasons, but it can readily oxidize, producing surface color changes.</p><p><br /></p><p>So I am not sure if "Toning" is the proper word to use for the color change in gold.</p><p><br /></p><p>Jim[/QUOTE]</p><p><br /></p>
[QUOTE="desertgem, post: 761932, member: 15199"]In relation to gold toning. The color of gold is determined by relativistic effects. Metals such as silver absorb and reflect photons of color energy due to an "electron sea" on their surface. Gold would also be a silver color except for this relativistic effect. Gold absorbs a "blue" energy photon and reflects the "redder" energy photon as an internal electron moves from the 5d to 6s orbit. Gold atom shifts the frequency enough to put the photon in the visible color range while a silver atom does not. This color of gold can vary as any surrounding atoms of non-gold alters their composition through oxidation. Gold itself does NOT form a stable oxide below thousands of atmospheres of pressure oxygen, so any color change of gold occurs because of the internal energy relationships of the atomic shells of the atom. There are quantum aspects as to velocity of electrons in more electropositive nuclei such as gold ( color ) compared to silver ( basically colorless), but the better physicists can probably work through that. Copper also has a color due to similar reasons, but it can readily oxidize, producing surface color changes. So I am not sure if "Toning" is the proper word to use for the color change in gold. Jim[/QUOTE]
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