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Beware of rainbow toning
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<p>[QUOTE="-jeffB, post: 2117336, member: 27832"]I'm betting that, if you investigate this carefully enough, you'll find that it's NOT <i>fully</i> reversible. The sulfide ions don't attach solely to the coin's surface without disrupting the crystal structure; to get colors, you need layers many atoms thick. When you remove those sulfide ions, the silver atoms don't go back to their original positions.</p><p><br /></p><p>I'll grant that it may be possible to produce a formulation that doesn't damage pure metal, even on extended exposure; such a "safety dip" seems like it would be a big win. But if you let a coin tone deeply enough, or if you send it through enough toning-dipping cycles, you're going to lose the fine surface structure that produces luster.</p><p><br /></p><p>All the same, I look forward to seeing your results. I've thought of doing such a series of experiments myself, but that's not likely to happen. (Besides, I'm still miffed that I don't have an XRF gun or AFM of my very own. Yet.)[/QUOTE]</p><p><br /></p>
[QUOTE="-jeffB, post: 2117336, member: 27832"]I'm betting that, if you investigate this carefully enough, you'll find that it's NOT [I]fully[/I] reversible. The sulfide ions don't attach solely to the coin's surface without disrupting the crystal structure; to get colors, you need layers many atoms thick. When you remove those sulfide ions, the silver atoms don't go back to their original positions. I'll grant that it may be possible to produce a formulation that doesn't damage pure metal, even on extended exposure; such a "safety dip" seems like it would be a big win. But if you let a coin tone deeply enough, or if you send it through enough toning-dipping cycles, you're going to lose the fine surface structure that produces luster. All the same, I look forward to seeing your results. I've thought of doing such a series of experiments myself, but that's not likely to happen. (Besides, I'm still miffed that I don't have an XRF gun or AFM of my very own. Yet.)[/QUOTE]
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