Log in or Sign up
Coin Talk
Home
Forums
>
Coin Forums
>
Coin Chat
>
Arresting corrosion on copper?
>
Reply to Thread
Message:
<p>[QUOTE="BadThad, post: 2416938, member: 17261"]Generally true, but not completely. Verdigris in itself can provide feed materials. Think about it on a micro-scale, verdigris contains micro-components (i.e. acids, anions, etc.) that can contribute to a self-sustaining reaction. This is well known by ancient collectors with coins that have hydrochloric acid induced verdigris (i.e. the horrible, incorrect term called 'bronze disease'). In chemistry, reactions occur in equilibrium, meaning they are never totally to completion. There is always evidence of the starting materials remaining, they may be minuscule, but they are there at some level. As things shift around due to the equilibrium, you have activity.</p><p><br /></p><p>Verdigris is quite complicated, while the formation forces at work, primarily on a macro-scale with air and water, you must also consider the dynamic electrochemistry involved. All metals exhibit micro-currents within them. Electrons are constantly flowing and the effect is exacerbated by temperature fluctuations. This drives electrochemical reactions on a micro-scale, which, given enough time, can eventually build verdigris to where you can see it if feed materials (old verdigris) are present.[/QUOTE]</p><p><br /></p>
[QUOTE="BadThad, post: 2416938, member: 17261"]Generally true, but not completely. Verdigris in itself can provide feed materials. Think about it on a micro-scale, verdigris contains micro-components (i.e. acids, anions, etc.) that can contribute to a self-sustaining reaction. This is well known by ancient collectors with coins that have hydrochloric acid induced verdigris (i.e. the horrible, incorrect term called 'bronze disease'). In chemistry, reactions occur in equilibrium, meaning they are never totally to completion. There is always evidence of the starting materials remaining, they may be minuscule, but they are there at some level. As things shift around due to the equilibrium, you have activity. Verdigris is quite complicated, while the formation forces at work, primarily on a macro-scale with air and water, you must also consider the dynamic electrochemistry involved. All metals exhibit micro-currents within them. Electrons are constantly flowing and the effect is exacerbated by temperature fluctuations. This drives electrochemical reactions on a micro-scale, which, given enough time, can eventually build verdigris to where you can see it if feed materials (old verdigris) are present.[/QUOTE]
Your name or email address:
Do you already have an account?
No, create an account now.
Yes, my password is:
Forgot your password?
Stay logged in
Coin Talk
Home
Forums
>
Coin Forums
>
Coin Chat
>
Arresting corrosion on copper?
>
Home
Home
Quick Links
Search Forums
Recent Activity
Recent Posts
Forums
Forums
Quick Links
Search Forums
Recent Posts
Competitions
Competitions
Quick Links
Competition Index
Rules, Terms & Conditions
Gallery
Gallery
Quick Links
Search Media
New Media
Showcase
Showcase
Quick Links
Search Items
Most Active Members
New Items
Directory
Directory
Quick Links
Directory Home
New Listings
Members
Members
Quick Links
Notable Members
Current Visitors
Recent Activity
New Profile Posts
Sponsors
Menu
Search
Search titles only
Posted by Member:
Separate names with a comma.
Newer Than:
Search this thread only
Search this forum only
Display results as threads
Useful Searches
Recent Posts
More...