Question related to acetone cleaning

Discussion in 'Coin Chat' started by blackarrow, Nov 5, 2018.

  1. blackarrow

    blackarrow Member

    Hello,

    I found a great post from Doug on using acetone to clean coins. Right now, I have 3 silver coins which are already 12 hours in acetone, and I will take them out in another 12 hours, rinse them two more times in clean acetone and I hope there will be some difference. There are some photos of each coins I took before putting them in acetone.

    This some pvc residue on one coin, and for other coins, I could not find out what kind of residue is on them exactly. In the post I mentioned, it says that acetone is not very good for ordinary dirt and grime.

    Would it be wise to first soak a coin in lets say distilled water (or 2 times distilled water) to try to remove the dirt and grime (of course, just dipping, without any kind of brushing or wiping) and then continue with acetone procedure? What about soapy bath (distilled water and just little bit of soap) instead distilled water only?

    Is this procedure for silver coins only or should it be used on aluminium, stainless stell, zink etc. coins?
     
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  3. eddiespin

    eddiespin Fast Eddie

    Soap will dull the surface and freak out a discriminating eye. Toning of course being superficial, there are some who maintain it even flattens out any toning. Acetone will remove most glues, tapes, or of course nail polish, but that's about it. Use distilled water of course to remove dirt.
     
  4. blackarrow

    blackarrow Member

    Should I then bath the coins in distilled water first, and go for acetone? This way, I should be able to clean (hopefully) both dirt and any glue, tape or pvc residue.
     
  5. eddiespin

    eddiespin Fast Eddie

    Sure. As a general rule of thumb, always do the least invasive first.
     
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  6. blackarrow

    blackarrow Member

    Thanks. Any idea how long should the coins stay in distilled water/acetone? Also, should I try this on zink, copper, aluminium coins as well?
     
  7. Jaelus

    Jaelus The Hungarian Antiquarian Supporter

    Acetone cannot penetrate dirt. If you have PVC residue or the like and it is underneath dirt on the surface of the coin, guess what happens if you put the coin in acetone. Nothing. For dirty coins you have to soak in distilled water first, for this reason.

    You work top down removing layers of contaminants. Dirt and grime, then adhesives and oils, then undesirable toning like cloudiness (if you are dipping).
     
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  8. SlipperySocks

    SlipperySocks Well-Known Member

    Can you share his post? I am getting ready to practice on a few junk coins and would like to read it. Also, please share your results and soak times in water once you are done. Thanks
     
  9. blackarrow

    blackarrow Member

    https://www.cointalk.com/threads/proper-acetone-procedure.193708/

    The second post describes the procedure. I will share the results.
     
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  10. desertgem

    desertgem Senior Errer Collecktor Supporter

    Try to show a before and after photo. Jim
     
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  11. GDJMSP

    GDJMSP Numismatist Moderator

    I've written about it so many times I can't recall for sure if I mention a few points in the various posts on the subject. But when it comes to properly cleaning coins the hard part is identifying what you need to do in order for it to be effective. This knowledge only comes with experience, nobody can teach it to you, nobody can tell you with words how to identify this or that - you simply have to learn it yourself. But what's been suggested in this thread is how you do that. When ya don't know, start at the top and work your way down the list.

    And also remember that sometimes a little agitation can help when things don't or won't come off with just soaking. Soak the coins for a while, but after a few hours pick 'em up by the edges and swish them around some. Then soak them some more, and then maybe swish them around some more. The agitation will help loosen and remove top layers and let the water, acetone, xylene get to the next layer down. And you may have to do this at every step along the way, with each of the liquids.

    As for soap, generally it's a bad idea because soap always leaves residue behind and it is not an inert substance. Now you can get the residue off if you know what you're doing but it's an added risk that you don't need to take.

    Properly cleaning coins isn't something that can be rushed. Yeah sometimes it does go quickly and easily, but other times it doesn't. It all depends what's on the coin, how thick it is, if there are multiple things, etc etc. So sometimes you simply have to settle down and take your time if you don't want to harm the coin. And time is all it's gonna cost ya, time is the price one pays for doing things correctly in all things in life.
     
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  12. Oldhoopster

    Oldhoopster Member of the ANA since 1982

    I can't agree more.
     
  13. SlipperySocks

    SlipperySocks Well-Known Member

  14. halfcent1793

    halfcent1793 Well-Known Member

    Anything acetone will do, it will do quickly. A couple of minutes or less. It will not remove PVC “residue,” which is not residue but corrosion.

    PVC, by the way, does nothing to coins unless, in the form used for water pipes, it scratches them. The phthalates added to PVC to make it flexible are acidic, and they corrode the coin. They are also called endocrine disrupters that can cause birth defects and in some places are illegal to have in anything that contacts pregnant women or babies.
     
  15. calcol

    calcol Supporter! Supporter

    A short exposure (less than an hour) of more reactive metals like copper, zinc and aluminum to high-grade acetone is unlikely to hurt them. I recommend only reagent grade acetone be used. Impurities will be in higher concentration in lower grades of acetone. Concern with longer exposure is that some of the impurities sometimes found in acetone are phenol, formaldehyde, acetaldehyde, and acetic acid. These will attack reactive metals.

    I recommend that coins that have had an acetone bath be rinsed with fresh acetone and allowed to air-dry rather than be rinsed with water, which may leave a coating or spots. Remember acetone and its vapor are extremely flammable. Do not reuse acetone.

    Be aware that even a short exposure of copper coins to acetone can noticeably alter their appearance. This is because brown color that is assumed to be toning may be due in part to dark colored dirt, oil, wax, varnish, etc. These substances will be removed, and the coin color will be different after its acetone bath. The new color may or may not be an improvement.

    If something is attached or applied to a coin (hologram, gem, artificial color, etc.), acetone may remove it.

    Cal
     
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  16. blackarrow

    blackarrow Member

    So, this is the first result. I am really bad at taking photos as you can see, but next time it will be better. All of the three coins were dipped in acetone for around 24 hours. After that, they were rinsed 2 times in clean acetone and let dry. The first difference which probably can not be seen on photos is the stronger luster on all coins.
     

    Attached Files:

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  17. Oldhoopster

    Oldhoopster Member of the ANA since 1982

    As others have said, acetone will remove many organic materials, but does not affect the toning/tarnish. The remaining discoloration on your coin may be related to environmental toning, so you may have gone as far as possible with acetone.

    Also,the 2 Reichsmark coins in your pic have a .625 Silver, .375 Copper composition. As Doug mentioned above, the key is knowing the correct method to lightly clean the coin without damaging the surfaces. It could be a challenge to find the right method with that composition. I would recommend leaving your coins "as is" unless you have a lot of experience and/or practice on some of the less expensive 2 reichsmark from the later 30's rather than the Luther's.
     
  18. GDJMSP

    GDJMSP Numismatist Moderator

    You are of course correct. But when people say PVC residue, it is the phthalates that they are referring to. PVC residue is nothing more than the name commonly used for phthalates.

    If you just laid the coin down flat, yes that might happen. But, if you followed my directions and stood them on edge to dry, all excess water runs off the coin immediately and the rest dries without leaving any spots or reside of any kind.
     
  19. GDJMSP

    GDJMSP Numismatist Moderator

    Yes, they are all lighter in color. But they are not lighter because you're seeing more luster, they are lighter in color because the acetone removed some of the substances accumulated on the coins. If I had to guess I'd say that those coins were exposed to smoky air for a long time. It could have been caused by indoor fireplaces, gas heat and or stoves in the home, the owner being a smoker, or air in the location (town) being smoky from industrial causes. And there's probably a couple of other possible causes as well. Even the foods and the cooking methods commonly used by the owner could cause it.

    Only two of those coins even have a any luster remaining - the 1st and the 2nd. The 1st has very, very little, and 2nd a little more. And yes I agree it is more readily visible on both in the after pics. But it was also visible on the before pics. My point with this comment is that yeah I agree you can more readily see the luster there is. But I want to make sure you're not equating the lighter color with actually being luster - because it isn't.
     
  20. Kentucky

    Kentucky Supporter! Supporter

    Regarding coins and solvents...

    Starting with water is always good. Distilled if you wish, but I like to run the water in a sink until it is HOT then let the hot water play over the coins for 15-60 seconds. After this, you can rinse in distilled (or deionized) water, but I always like to blot the coins dry. Afterwards, acetone or xylene or both. For silver a quick (< 1second) dip in eZest is pretty non-invasive.
     
  21. blackarrow

    blackarrow Member

    I agree. As said before, my skills with photo taking are quite bad and I will try to improve that. Since it is hard to see any real change if the photos are just lighter overall.
     
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