The third from the left is known as a Nishu Gin Gold Bar Coin, Japan, 2 Shu. I am pretty sure of it. I will do some more research on the others and get back to you if I figure them out.
They do look authentic as far as I can tell. If by any chance they were counterfeits, they're really good ones. How much do you want for them, priced individually?
I'm concerned about the second silver piece - the surfaces are strange. If you can wait a few hours, I'll look them up in the appropriate references (unless someone beats me to it!) I would strongly recommend you purchase this book: http://www.authorsonline.co.uk/book/1129/Early_Japanese_Coins/paperback/ Very inexpensive, and with a wealth of information on both the precious and base metal issues.
1 - Ansei Era. AR Ichi Bu Gin. Edo mint. Struck 1859-1868. D sakura inverted. Hartill, Japanese 9.82; JNDA 09-52 2 - Bunsei Era. AR Nanryo Gin. Edo mint. Struck 1824-1830. Hartill, Japanese 9.75; JNDA 09-48 (I think it may be fake) 3 - Man'en Era. AV Ni Shu. Edo mint. Struck 1860-1869. Hartill, Japanese 8.51; JNDA 09-44 4 - Meiji Era. AV Ni Bu. Edo mint. Struck AD 1868-1869. Hartill, Japanese 8.32a; JNDA 09-29 I will double check these when you get weights.
ok, #1 8.5 Grams 22.5mm by 15mm #2 7.5 Grams 21mm by 13mm #3 .8 Grams 11mm by 6mm #4 3 Grams 19mm by 11mm