You might try putting one of them in a dish lined with tin foil and pour a cup of boiling water with 2 Tablespoons Baking Soda + 1 Tablespoon Salt on it. The reaction removes sulfates like the black spots on silver and the boiling water helps with the dirt. Worth a try ?
Glad you've been paying attention But I didn't mention it because he should not use it. As I said, if it is raised up - it's not PVC and acetone will not help so there is no sense using it.
Has anyone used other solvents on coins? Such as Diethyl ether, Dichloromethane, Hexanes, Benzene, Ethanol, ect. Halogen solvents I doubt would be a good idea. However, since I am not brave enough to try it on my coins I can not say for sure. I have played a bit with THF (tetrahyrdofuran) on a few junk silver quarters and didn't see any noticeable damage (I dipped it for a minute then dried it in a 50*C oven overnight).
badthad recommends water, acetone, and then xylene (or toluene) in order (but I don't remember which direction) due to the polarity. That would be to remove dirt and PVC plasticizers. It will do nothing for verdigris.
So Safely, I think Thad's Verigone now being replaced with the Verdi-Care are the best chance. However, some levels of verdigris damage is beyond any help.
Yes, if there's copper in the coins, it's probably verdigris. DO NOT USE ACIDIC FLUIDS SUCH AS LEMON JUICE OR CATSUP! Both will permanantly damage the coin surface resulting in cleaned (and ruined) coin.
I have tried about every solvent known to man. Depending on the problem, most are completely ineffective and may change the patina.
It's called the Polarity Ladder: water>acetone>xylene Verdigris will generally not be removed by following the ladder.
BadThad, what effect did pyridine have (or other amine solvent if you did try it)? Have you tried peroxides? (i.e 3 to 30% hydrogen peroxide)?
Amines are far too harsh on the surfaces. Pyridine stinks to high heaven too! Amines will lighten the surfaces. Peroxide is even worse. Collectors using such solvents will usually end up with a damaged coin.