Coin pages and three ring binders

Discussion in 'Coin Chat' started by Hydr, Mar 24, 2019.

  1. GDJMSP

    GDJMSP Numismatist Moderator

    @Hydr -

    I don't think you understand what the problem is with PVC contamination. But that's understandable as there are a whole lot of collectors who don't.

    The issue is very simple really, vinyl puts off a gas that contains large amounts of hydrochloric acid. And when that gas comes into contact with the coins it condenses and turns into a liquid form. That acid is then constantly eating away at your coins. Eventually it will destroy them.

    Now if you don't want to clean the coins by rinsing them in acetone, that's fine, that's your choice to make. But be aware, if you do not clean them you cannot store them anywhere near any other coins you may have or else you will expose those other coins to the very same thing because the liquid form itself also puts off additional gasses. So if you don't want to clean the coins, you need to get rid of them.
     
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  3. GDJMSP

    GDJMSP Numismatist Moderator

    Cardboard and all paper products, and yes this includes cardboard 2x2s, (except those of archival quality) are bad for the same kind of reason that PVC is - it's because cardboard and paper also put off gasses, only this time the gasses contain large amounts of sulfur. And sulfur will cause the coins to corrode over time and become permanently damaged.

    Proper coin storage is fairly straightforward, but it's also complicated at the same time. It's simple in that only inert materials should ever be used when it comes to proper coin storage. And it's not direct contact with the coins that you have to worry about - it's the gasses, the very air, that you have to worry about. This means that nothing but inert materials can be anywhere near your coins !
     
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  4. John Skelton

    John Skelton Morgan man!

    Where would you get archival 2x2s? I've never noticed any that mentioned being archival.
     
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  5. Stevearino

    Stevearino Well-Known Member

    I checked out the binder that @Bayern gave a link to. It's made of polyester. Do any of our knowledgeable CTers know if polyester outgasses or if it is inert?

    Steve
     
  6. LaCointessa

    LaCointessa Well-Known Member

  7. Maxfli

    Maxfli Well-Known Member

    This is why every raw coin I buy gets a bath in acetone, even if the coin looks pristine. I have no way of knowing how or where the previous owner stored the coin, and whether or not there are invisible contaminants lurking on its surface.

    That's actually the worst solution. Either clean your polluted coins, or get them as far as possible from any coins you own that aren't contaminated.
     
  8. Hydr

    Hydr New Member

    the acid is actually every where, not just on coins. I try to eliminate contaminants but there is also an adage "The dose makes the poison"
     
  9. Kentucky

    Kentucky Supporter! Supporter

    ...speaking of chemistry...the problem with PVC (polyvinyl chloride) is that it is really a rigid solid and to make it flexible they pump in lots of a plasticizer that is kind of like an oil, it makes it flexible, but it can exude over time and that is why whatever you have in contact with it gets sticky. Now, the plasticizer really isn't acid, but it can trap lots of stuff and hold them close to the coins. The PVC by itself can decompose over time and give off what Doug was talking about, hydrogen chloride gas, which forms hydrochloric acid when dissolved in water. If the PVC is giving off hydrogen chloride, it is probably starting to look yellowish. Acetone is pretty cheap and you really should consider giving all your coins a bath. You can put lots of them in a container (glass please) and clean them all at the same time. Just remember to change the acetone a few times and dispose of the old stuff carefully. The safest plastic to use would be polyester (PET, polyethylene terphthalate, terelene, etc.) but polyethylene and polypropylene should be safe too.
     
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  10. CoinCorgi

    CoinCorgi Tell your dog I said hi!

    Polywannacracker?

    [​IMG]
     
  11. harley bissell

    harley bissell Well-Known Member

    some pages I've seen feature seven holes - three each at top and bottom and one in the center. Some of the used three hole binders I've used don't exactly match the outside holes. By offering a selection the pages fit whatever you've got. If you are worried about tarnish avoid the cardboard flips and use the plastic flips made for coins. Since I rarely have to deal with anything but worn coins the paper cardboard flips work fine for me. good luck
     
  12. twoshadows

    twoshadows Member

    I quit using the coin pages years ago as I found they create heavy binders and some storage issues. I now use 2X2 boxes or Dansco albums for space saving and coin protection. Almost all my "precious" coins,(high grade) regardless of value or denomination are placed in airtites as I am not fond of toning and I have some old storage boxes that will hold 48 airtites in each. I go out of my way to try and protect each and every coin! I figure if it was worth buying it is worth protecting.
     
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  13. Hydr

    Hydr New Member

    binders have another issue, if they are thick, it will be not smooth when turning pages.
    at first I thought it depends on the design of rings and the material of pages, later I find that for thin binders page turning is very smooth
     
  14. Hydr

    Hydr New Member

    Good to know.

    So the sticky thing itself is not any form of HCl (hydrochloric acid)? I guess the sticky thing also contains no water so there are not much HCl dissolved in it. Also acetone is for washing off sticky residuals, it has nothing to do with HCl.

    It is hard to buy 100% acetone online, when I search "acetone" I find a lot of de-gumming products, they are not 100% pure acetone, some products even advertising "0% acetone"
     
  15. GDJMSP

    GDJMSP Numismatist Moderator

    The thing that Kentucky left out of his explanation is that water exist in the air in the form of water vapor. And since the hydrogen chloride gas goes into the air and mixes with that water vapor the hydrochloric acid is formed when it condenses on the coins.

    As for color, PVC residue changes color. When it's first deposited on the coins it is clear and for all intents and purposes invisible to the naked eye. But with time the color changes, and changes continuously. It can have a white, yellow, brown, green, and eventually even black cast to it. It all depends on how long it's been there and the specific environment where the coins are located.

    I cannot speak as to what is or is not available in your country. But here in the US pure acetone is readily available in any paint store or hardware store. And it is very inexpensive.
     
  16. Hydr

    Hydr New Member

    According to Kentucky's explanation:
    pages emit hydrogen chloride gas + water in the air = HCl
    pages emit plasticizer = sticky residual

    If I throw away PVC pages and keep the coins, there are only sticky residual, will be no more new HCl, and there are supposed to be no HCl left in the residual because the residual does not contain much water.

    this is the optimistic view:chicken:
     
  17. Kentucky

    Kentucky Supporter! Supporter

    ...close. The hydrogen chloride gas can dissolve in the plasticizer that deposits on the coins as can some atmospheric moisture, making hydrochloric acid that would be held close to the coin. Have you tried to buy acetone on Alibaba or Made-in-china.com
     
  18. Hydr

    Hydr New Member

    the contaminated coins are most common types, I'll try to clean them if I can get acetone. As long as the dose of HCl inside residual is not enough to cause visible corrosion to my new collections..
     
  19. GDJMSP

    GDJMSP Numismatist Moderator

    If you'll simply follow the directions I provide in the thread I linked to, it will remove all of the harmful contamination.

    You need to understand something here, ANY residue on the coins will ABSOLUTELY cause corrosion in time. You may not be able to see it now, but in time you will. In other words, there is no question of IF it will, it is only a question of WHEN it will.
     
    Kentucky likes this.
  20. Stevearino

    Stevearino Well-Known Member

    @Hdyr
    You've received a lot of valuable and trustworthy information in this thread. I hope you will put it into practice and not keep coming back with reasons why it is not practical. The ball is in your court, my friend.

    Steve
     
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  21. CoinCorgi

    CoinCorgi Tell your dog I said hi!

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