Trying to draw a firm line between "solid" and "liquid" for mixtures is silly, anyhow. If you can't point to a phase transition with an associated energy change (heat of fusion), there's not a firm boundary. In science class, there's "solid, liquid, gas", then eventually "plasma" gets added 00 but even for pure substances, you go on to crystal phases and allotropes and endless other complications. With mixtures, you get gels, colloids, emulsions... In the real world, between "solid" and "liquid", there's "gunk".
I spoke with my friend who is a chemist in the lubricants division for Chevron, and he says liquid, so I'll accept that I'm wrong... until I can convince him that it's a solid.
In the end does it really matter if grease is a solid or a liquid ? What I mean is this, grease is absolutely different than water because of its viscosity. And even if the end result a coin being struck through water is similar in some ways to one that is struck through grease, it's going to be somewhat different, and maybe very different at least in some cases, as a result of that viscosity. Here's why. First forget the science part of it and think about the common sense part of it. Water and grease both, if pressure is exerted on them between 2 soild objects, will be squeezed out. Maybe not 100% squeezed out but the majority of it will be. And if you think that won't happen then think again. You guys know what finning is don't you ? Finning occurs when a coin is struck with too much pressure. As a result of that excess pressure, a solid, the metal of the coin planchet, is squeezed out in the tiny gap that exists between the planchet, the dies and the collar. This solid is literally pushed up through that tiny gap so that it remains and a thin fin is attached to the rim of the struck coin. So, if this can happen to a solid, and there can be no argument that the metal is a solid, what do you think would happen to grease or water ? And this happens purely because of pressure, and it doesn't matter if it's a solid or a liquid - it still happens. And rather obviously it's going to take less pressure for it to happen with water or grease than it does with metal. The question then becomes why then does grease affect a coin the way it does when that coin is struck through grease ? The obvious answer is because it is a substance that is between the dies and the planchet, and any substance that is between them is going to have some effect. No matter what it is it's not going to be like it wasn't there. And that's where the difference in the viscosity of grease and water comes into play. While both water and grease can have particles of other substances like dirt and tiny metal particles suspended within them, because of its high viscosity grease is almost certainly going to have more of them than water will. Grease is stuck there on the parts of the press allowing more and more particles of other substances to become stuck in that grease over time. With water that's not as likely to happen because most particles that get into the water settle out very quickly and with grease they don't. So, if a blob of grease happens to fall on a die, the particles that are stuck to and in that grease go with it. And when the coin is struck most of the grease will be squeezed out but some of those particles are going to remain behind because they won't move as quickly as the grease does. And those particles and the remaining grease both affect how the coin will look. In effect the particles are strike-throughs, many of them, but so tiny that you can't differentiate one from the other. And whatever remains of the grease is too. But if a drop of water falls on a die, which is pretty unlikely to begin with but for the sake of argument we'll say one does, it's not going to contain as many particles as the grease does. Sure, it will still have an effect on the struck coin, but it's not going to be as pronounced as the grease is. Now all of that's just common sense, not a whole lot of science really involved. But you could add the science in there if you wanted to, you could measure the weight of the grease and water, measure the viscosity, the size and weight of the particles, the principles of adhesion, the compression factors of all substances involved, and all the other stuff that I don't even know about. But in the end it's gonna be the same thing. The grease will have more effect than the water does. It's merely a matter of degree.
Problem is, "common sense" really only gets you so far when it comes to rheology. Newton covered the "common-sense" parts, but there's a reason why so many fluids are called "non-Newtonian". Since I haven't even taken the classes, never mind worked in the field, I can't help much with those non-common-sense aspects. But taking Doug's point about particles, let me ask this: isn't there a good chance that a trickle of thin, not very viscous liquid, running across machinery where some parts are covered with grease, but others covered with dust, might actually pick up more particles (per unit volume) than the grease has? The answer, of course, is "who knows?" I don't know where the water would come from, what it would run across to get to the planchet, and how much debris it would pick up along the way. But I have just as much right to speculate as the next guy.
No argument. But, probability pretty much says grease will have more of an effect more often than water does. The bottom line, anything that get's between the dies and the planchet is going to have some effect on how the coin turns out, it's just a matter of degree.
We need think about aqueous solutions and suspensions too. Things like coffee, cola, milk, honey, jelly, etc. ... yes, even beer. Good chance these have gotten on planchets or dies. Perhaps these things are confined to the lunchroom today, but in the past, mint workers probably could take their drinks and snacks into the machinery rooms. Not too big a stretch to imagine a bottle of cola or cup of coffee falling into a bin of planchets ... sometimes maybe with a little deliberate help. Having solutes or particles in the water can make a big difference. Evaporation rates can be dramatically lower, the liquid may form a higher-domed bead, viscosity will be increased, particles or crystals may start to precipitate, solutes may react with metal, adhesion of the bead to metal may be greater, etc. Put a drop of pure water and sugared cola on a quarter, and see which lasts longer and which leaves a residue. Cal
I was striking some coins today and performed a test. With the planchet sitting in the coining chamber, I put a small drop of water on the planchet. The drop was located were there was a recess in the die above it. The recess was a facial portrait. I expected that this recess would trap the water when struck. The result was that the entire coin was fully struck except where the water was trapped. The facial portrait details were missing and there was a smooth shallow depression on the struck coin where the face was supposed to be. This was as I had expected. Water is incompressible, and if it has nowhere to escape, it will make in impression in the planchet. If the drop was near the edge and not in the center, it might squirt out at high velocity before interrupting the striking.
Thanks for confirming, that is exactly what I expected to happen. Question: did this have the typical appearance that we associate with coins "struck through grease"? That is, if we were looking at a coin from the mint, would there be any significant difference between a "greaser" and a "water" coin? My suspicion is no, probably not.
The area where details were obstructed by water had the same surface texture and general appearance of the original planchet. Grease tends to stick to the die face and spread out more after repeated strikes. It also typically has metal particles bound in it. Water would dissipate rather quickly after repeated strikes. The water strike-through area is a little more shiny than the typical grease strike-through.
I think what I'm trying to ask (and was implying without saying): planchets at the mint tend to be somewhat rough (from tumbling, handling, etc), with a large amount of contact marks. If you get a blank planchet, or a planchet struck sufficiently off center, you'll see that. When we see a "struck through grease" coin, it tends to have a rough appearance with a lot of tickmarks. Would a "struck through water" coin have the same rough appearance? My suspicion is that yes, it would. From what you say, that the water struck coins had the same texture as the original planchet, leads me to believe that generally, "struck through anything" will have roughly the same appearance and will thus be virtually indistinguishable to the collector.