Calling on experts: What's the matter with Ben ? Here is my 1961 PF67 Franklin half dollar slabbed. If you notice around the back of the head and the front of the face the coin has begun to......well I don't know. Assistance is greatly needed to figure out 'What's wrong with him'.
Not if it was submitted shortly after it was dipped as it usually takes a while for that residue to show up on the coin.
It could be the start of toning but I would tend to agree with Mainebill on the improper rinsing of being dipped.
Ehhhh, maybe, maybe not. As said it could just be toning, and yes coins do tone in the slab. If it's dip residue it will often have a slightly gritty look to it, if you look at it with a loupe. It doesn't always, but quite often it does. Other times it will have a filmy look to it. So look, see if it does or not. But if it's toning, neither of those "looks" will be present, it'll just be a different color in those areas. Another thing that may, stress may, help you make the determination is examining, thinking about your storage methods. In other words if you do not follow proper storage procedures then toning can be quite likely. But if you do follow them, then it should not be. For with proper storage toning usually takes a long time.
I've looked at both side of the head with two different loupes. There is no gritty look on either side and no film. When looking at the edges of each area, they look to be slightly darker than the center of this discoloration. As for storage, I keep all my slabs in a closet, in a storage box. Thoughts now ?
What kind of storage box, and what else, if anything, do you keep in this box with the coins ? And do you also keep silica gel packs in this storage box, and replace or recharge them as needed ? What I want to know is what your box is made of, what kind of material. Does it have a lid that seals it ? Do you keep any paper or cardboard, of any kind, in the box ? And yes that includes original mint packaging. And do you keep anything else, anything at all, in this box ?
This Franklin is in a metal lock box, stacked with other Morgans and Peace dollars, all slabbed. There are no silica packs in the box. The box is lined with your basic paper towel, bottom and sides not top. There are about 100 slabs in the box, that's all. The box is in the back on my closet dry no humidity in the room.
Well, then I'd say that's your problem. You need to get rid of the paper towels, and get yourself one of these - http://www.jpscorner.com/silica-gel-humidity-control.html You don't want anything in the box that is made of, or has any paper or cardboard of any kind. And even if you think you don't need that silica gel pack, you do. And you have to check it every now and then and recharge it as necessary.
Doug, like most people here, my coins are stored in a SDB. Most are in airtites or slabs stored inside the PCGS slab boxes. My SDB also has important documents, passports, ect. Those papers need to go? I need another SDB? One for coins, one for papers?
Afraid so. All paper and cardboard products, (except those specifically labeled as archival quality) contain chemicals that are harmful to coins. Also, a great many banks, though I won't say all of them, have a dedicated humidifier system for their vaults. This is because paper is ideally stored in an area with high humidity, and most of what is in safe deposit boxes is paper. However, since humidity is one or the primary enemies of coins, storing coins in a SDB can be quite risky. So you need to use the silica gel packs in your SDB and check them regularly.
To piggyback on Doug's comments, I had a hard time with my ASEs and unwanted toning even with silica gel packs. I picked up a cheap hygrometer on Amazon so I could monitor the humidity levels. I ended up purchasing the 750 gram canister and got the humidity level to about 20%. Be sure to recharge the silica packs regularly.
I have four of the items pictured in Doug's original response. You need to recharge them about every 3 months, 300 degrees in your oven for about 3 hours. They last indefinitely.
I "used" to use those specific containers..................until one got bumped in the SDB and spilled its contents all over the box. Not much good to me then. Over the passed 44 years, after having collected and stored coins in 2x2's, storage boxes, safes, and safety deposit boxes in California, Vermont, Texas, and Colorado, I've yet to experience any discoloration due to environment or whether or not papers and wood outgassing (I built a fake back in a cabinet in a wet bar with stained plywood and wood standoffs with velcro fasteners) occurred in or around the stored coins. Never. However, I have experienced discoloration on coins due to something which was physically on the coins surface over both short and long periods of time. Slabs are not air tight containers but they are also not open windows in that do not allow air to "flow" freely within the slab. As such, any movement of air within that slab is barely even perceptible. My guess is that whatever is occurring with the OP's coin is a direct result of something coming in direct contact with that coin before it was slabbed. The only resolution is to have the coin conserved by NGC to properly remove the contaminant. However, since it's a relatively common proof coin with a relatively common grade I would not concern myself with the expense unless the coin had some sentimental value associated with it. All my opinions are based upon experiences through observation and not scientific fact.
19Lyds, let me ask you a question - do you carry insurance, any insurance ? I'm pretty sure that the answer is going to be yes, so I'll ask another question - why ? And I'm pretty sure the answer to that is - just in case. Well that's what proper storage is with coins - insurance. Ya see, there are always stories, reports, anecdotes - pick your word - just like yours where people say I never did any of this and my coins never toned. But for every one of you, there is another and maybe 2 or 3 others who would say I did all the same things you did and my coins did tone. So how can this be ? And the answer to that is pretty simple, it's because even though you both think you did the same things, you didn't. There are a thousand variables involved when it comes to coins toning or not toning, maybe more than a thousand. And yeah, sure, in some cases when a coin tones it can be because there was something on the coin before you got it, and that's why it toned. But in every single case ? Nah, no chance. So why do some people's coins tone and some do not ? It's because of the variables. And literally everything is a variable ! So what to do ? I don't want my coins to tone so how can I prevent that from happening ? You take out insurance - proper storage - just in case.
Following up on the Franklin, since the toning has begun on the coin, should I just continue to allow the toning to continue ? See where it goes from here ? Is it going to hurt future value ? I have purchased the gel packs and have pulled the paper out of the box.