Proper acetone procedure

Discussion in 'Coin Chat' started by DLeach, Oct 19, 2011.

  1. SuperDave

    SuperDave Free the Cartwheels!

    By your numbers:

    1. If you are not actively treating something visible/notable on the coin - like visible green or haziness from PVC - a couple hours is ample as long as you "swish" rinse after so nothing redeposits from your original soak. Even at that I'm probably - as is my way :) - displaying excessive paranoia. For a coin you've no reason to suspect, 10 minutes is probably sufficient. For efforts against visible stuff you would reasonably assume acetone to be effective against - that list is shorter than it might appear - well, the worst PVC infection I've ever treated took a total of more than a week (168 hours) of actual soaking time and a couple weeks altogether.

    2. Use a bath of a type which will not allow the coin to lay flat. For me, that's various shotglasses keyed to the size of the coin. That way there's no question that both surfaces share the contact equally. It's also more conservative of acetone. I care not at all how much crud gets dissolved into a small amount of acetone because if it's that bad I'll probably use one or two extra soaks just to allay my fears of redepositing, after the coin looks fine visually.
     
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  3. -jeffB

    -jeffB Greshams LEO Supporter

    Good idea, for two reasons:

    1) Less likely to break if you knock it down, splattering flammable acetone everywhere.

    2) There's an ongoing debate here about whether acetone can damage copper coins. The paper that's usually cited by the "yes" side studied surfaces exposed to light; if there's anything to it, keeping your acetone in the dark while soaking things would help avoid the problem.

    I'd be nervous about putting acetone in a plastic container. I know it's supposed to be compatible with polyethylene and polypropylene, but I'd still worry about it dragging out plasticizers that could react with your coin surfaces.
     
  4. SuperDave

    SuperDave Free the Cartwheels!

    It's published scientific fact which can be duplicated by experimentation, just more difficult to do as an experimental numismatist because you have to arrange some....serious humidity. One could b0rk one's procedure sufficiently to duplicate it accidentally, but if you've that capability you probably shouldn't be handling acetone in the first place. :)
     
  5. desertgem

    desertgem Senior Errer Collecktor

    There is also a problem with peer review lacking. The paper is easy to find on the internet, but the research was seemingly backed by a company trying to show that using acetone to clean the end of copper pipes could induce corrosion before/after joining , whereas their product would not. Read it first if you have a physics or chemistry background before you decide. I have, and I am happily using acetone when needed, with no ill effects on the copper coins. Your Mileage may vary.

    It is similar to the stories that Coke(tm) can dissolve your stomach or "meat" . and that is true if your "stomach" is a glass container unlike your real stomach which is coated with mucus and organics from its epitheium and is protected from the acid.
    I suspect that the acetone story is appreciated by those who manufacture oil concoctions and such to clean copper and make that wonderful colorful toning :)
    I own no interest in any products named or un-named here.
     
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  6. -jeffB

    -jeffB Greshams LEO Supporter

    As I said: "ongoing debate". ;)
     
  7. SuperDave

    SuperDave Free the Cartwheels!

    It's pretty trivial to make copper the catalyst in a seriously exothermic oxidation of acetone (enough to make the preheated copper lose none of that temperature and stay red-hot), without the acetone actually igniting. That should be a hint even to the non-chemist (raises hand) of the potential relationship between copper and acetone.

    And since the article we're both talking about publishes specific procedure, it's easy to duplicate itself with or without peer review. More here:

    http://jes.ecsdl.org/content/147/11/4125.abstract

    None of this makes me unwilling to use acetone on copper. Far from it. Conservation is about exacting procedure, and avoiding light when employing acetone/copper isn't difficult.

    I'm going to specifically attempt to duplicate this myself during 2016, but I've a lot of pies in the oven at the moment so it's just another entry on the priority list.
     
  8. atcarroll

    atcarroll Well-Known Member

    If you have pvc drain pipes, don't dump acetone down the drain when you are done with it.
     
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  9. SuperDave

    SuperDave Free the Cartwheels!

    Unless, of course, you've decided to replace your city hookup with a septic field.
     
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  10. serafino

    serafino Well-Known Member

    I just throw the small amount of left over acetone on my cement driveway and it's gone in seconds. :)
     
  11. Silverhouse

    Silverhouse Well-Known Member

    I thought acetone could get off verdigris, if it doesn't then how do I get it off one of my MS coins without damaging it?
     
  12. Paul M.

    Paul M. Well-Known Member

    If it's copper, use VerdiCare. You may or may not like the result, though, because if the verdigris is advanced enough, it may have eaten into the metal.
     
  13. Silverhouse

    Silverhouse Well-Known Member

    It's a high ms barber dime. i haven't done anything to it. I am not experienced, so would sending it to NCS work?
     
  14. GDJMSP

    GDJMSP Numismatist Moderator

    Getting the verdigris off the coin is not the problem, that part's easy. As said, Verdi-Care will do that for you.

    The problem is this, once verdigris has formed that damage has already been done. You see, verdigris is not the cause of corrosion, verdigris is the result of corrosion.

    The powdery, flaky, sometimes even hard, greenish substance that you see - the actual verdigris itself - that is merely what the metal of the coin turns into as a result of the chemical reaction that caused the corrosion to begin with.

    In other words, there can be no verdigris unless some of the metal of the coin has already been eaten away. And that is damage that can never be repaired or removed. The only question is this - how severe is that damage ?
     
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  15. BadThad

    BadThad Calibrated for Lincolns

    VC is effective on ALL metals, not just copper.
     
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  16. serafino

    serafino Well-Known Member

    Thanks for updating us that you can use VC on all metals. I think many of us thought it was only for copper.
     
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  17. BadThad

    BadThad Calibrated for Lincolns

    Examples:

    [​IMG]
    [​IMG]
    [​IMG]
     
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  18. Silverhouse

    Silverhouse Well-Known Member

    A tiny speck, very very tiny. However if it will never grade.... Might as well get rid of it too. It's a nice dime. When I get the chance, I'll have to post a clear photo of it. It's a 1914 D Barber dime. I know I've posted up before, but I can't remember what forum it's in.
     
  19. GDJMSP

    GDJMSP Numismatist Moderator

    I think you're making an assumption here. I never said the coin wouldn't grade, didn't mention it at all.

    There are tens of thousands, maybe even millions, of coins with verdigris on them that have been cleanly graded by the TPGs. As well as coins that have had the verdigris removed.

    As I mentioned in my post above, yes any coin that has verdigris on it has suffered some damage, that cannot be denied. But the key element, as I mentioned, is the question of severity.

    Any damage to a coin, regardless of what it's caused by, (there are some exceptions however) is subject to the question of severity. For example, a coin cab be scratched and it will still cleanly grade. It's always a question of just how severe that scratch is. However, if it's big enough, and deep enough, in relation to the size of the coin in question, or sometimes if there is more than one scratch, it will not cleanly grade.

    It's the same kind of thing with verdigris - present or removed.
     
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  20. Silverhouse

    Silverhouse Well-Known Member

    Thanks for that. Looks like it may straight grade. We'll see on the next submission.
     
  21. rokwarm

    rokwarm New Member

    I really appreciate all of the time and energy that you veterans put into helping educate us newcomers
     
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