Franklin's - in Mint Sets, with White Corrosion

Discussion in 'US Coins Forum' started by USS656, Dec 8, 2019.

  1. USS656

    USS656 Here to Learn Supporter

    Besides the crystals being removed, not much changed with the white on the coin.
     
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  3. Michael K

    Michael K Well-Known Member

    Some kind of dip could remove it, or could damage it.

    "I been here 6 years and you hang my stuff in a bag on skid row?"
    "Hey Mick how come I been put out of my locker?"
    "Because Dipper needed it."
     
    Last edited: Dec 14, 2019
  4. -jeffB

    -jeffB Greshams LEO Supporter

    Looks like it may be time to put it up on eBay as the UNIQUE "MIME" VARIETY.
     
  5. mynamespat

    mynamespat Well-Known Member

    Largest known milkspot in the Franklin series
     
  6. desertgem

    desertgem Senior Errer Collecktor

    The silver cation, Ag+, reacts quickly with halide sources to produce the insoluble silver halide, which is a cream precipitate if Br- is used, a white precipitate if Cl
    is used. Wiki

    Since they were likely packaged outside of the mint, it would be PMD. The plastic film is not intended for long term storage, IMO. Jim
     
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  7. USS656

    USS656 Here to Learn Supporter

    Wonder what if anything can remove or neutralize it?
     
  8. desertgem

    desertgem Senior Errer Collecktor

    This from a chem site:
    Ammonia solution is added to the precipitates. <--coin instead


    original precipitate observation
    AgCl
    precipitate dissolves to give a colourless solution
    AgBr precipitate is almost unchanged using dilute ammonia solution, but dissolves in concentrated ammonia solution to give a colourless solution
    AgI precipitate is insoluble in ammonia solution of any concentration


    Best guess, but its bullion non the less. Use at own risk.

    Jim
     
  9. Kentucky

    Kentucky Supporter! Supporter

    Hey, first try 100% acetone overnight and then 100% xylene overnight. No harm from either of them!
     
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  10. GDJMSP

    GDJMSP Numismatist Moderator

    And each will dissolve various materials - so it's a good idea to at least try them. No clue if either will work though.
     
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  11. USS656

    USS656 Here to Learn Supporter

    Just put it into uncut acetone. Will have to figure out where to get xylene.
     
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  12. USS656

    USS656 Here to Learn Supporter

    will run over to home depot for the xylene later and change it out tonight
     
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  13. Kelly-Bob

    Kelly-Bob New Member


    According to Rick Tomaska in his book 'A guide book of FRANKLIN & KENNEDY HALF DOLLARS" . He explains that certain years of Franklin Proofs are plagued by 'Milk Spots' and he has determined from former Mint Workers that it is soap residue on the planchets that were not well and completely rinsed. They are pressured in by the press and are part of the coin metal now and cannot be removed.
     
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  14. Mountain Man

    Mountain Man Well-Known Member

    Someone in the packaging department had allergies and sneezed on them, after using a nose spray with ipratropium bromide in it. LOL Really, let us know how the soaks go.
     
  15. USS656

    USS656 Here to Learn Supporter

    9 hours in pure uncut Acetone - no noticeable impact

    Just placed in uncut Xylene for the night. Tomorrow will try ammonia if no noticeable difference.

    upload_2019-12-15_19-57-11.png
     
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  16. Kentucky

    Kentucky Supporter! Supporter

    Wow, that looks so crusty.
     
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  17. desertgem

    desertgem Senior Errer Collecktor

    This is not your normal milk spot. I believe he is talking about pinpoint or close spots from bad rinsing. This is a drop in the Pancake batter spot.
     
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  18. USS656

    USS656 Here to Learn Supporter

    after a couple hours seems like something is happening. God only knows what this will look like in the morning.

    20191215_222316.jpg
     
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  19. Razz

    Razz Critical Thinker

    Make sure to cover that glass so the liquid doesn't evaporate and redeposit the contaminants back onto the coin.
     
  20. USS656

    USS656 Here to Learn Supporter

  21. -jeffB

    -jeffB Greshams LEO Supporter

    Wow, I didn't think that gunk would budge with any organic solvent, but there it goes! Can't wait for tomorrow's photo...
     
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