Recently, had my nickel’s metal content tested with a handheld X-ray fluorescent (XRF) analyzer. These nickels are supposed to be 56% copper, 35% silver, and 9% manganese. I had different results. The analyzer was calibrated and operated by someone trained to use it. Anyone know anything about this or have opinions on the discrepancy?
When and by whom was the instrument calibrated? Those numbers are too far off, even with the tolerances. There will be be silver migration towards the surfaces and edges, but that is way off
The reading was recently taken by a family member. He’s employed by a major electrical switch manufacturer, and uses the XRF analyzers to test metal contents such as silver, copper, etc. that are used in the manufacturing process.
Send it to PCGS or NGC. I don't know what the tolerances are, or what premium someone would pay. If it was Cu-Ni it would be highly collectible. Fred Weinberg would be the man to ask.
That is very interesting! He's on here from time to time, if we tag him, @Fred Weinberg , maybe he'll chime in. Let us know how everything turns out!
I thought you had to mention his name three times...Fred Weinberg, Fred Weinberg, Fred Weinberg BTW, that XRF is going to give you a surface analysis including any crap that is on the surface.
I suspect that the analytics done by the mint at that time are more accurate due to the value of silver. Depending on whether your relative is a skilled user of the device or a chemical analyst educated on how the results have to be processed when there are differing amounts of the elements as some elements ( especially higher levels of lead and copper can cause inaccurate readings over other ( including silver). There are several papers that discuss this that can be found using google or the chem paper depositories ( charge) or publications by the XRF manufacturers. Here is the easiest one I could find by searching " xrf confusion with silver and copper" https://clu-in.org/conf/tio/xrf_080408/prez/XRF_02pdf.pdf Maybe if he contacted the XRF manufacturer and asked directly , they could help. Let us know as XRF machines are getting more available. Jim
I should have mentioned, if you took a few more random war nickles and they all gave the same reading , that problems with the XRF method was occurring, but if they other random ones were all 35% , that the original coin was off. Jim
Unfortunately, this is my only war nickel or I would. That being said, he’s tested other coins for me and their compositions have always been accurate.
Appreciate the feedback and wanted to provide more information on the XRF analyzer used. Here is a link to the XRF analyzer that performed the test: https://www.thermofisher.com/order/catalog/product/XL2PRECIOUS?SID=srch-hj-XL2PRECIOUS I’m told it’s very easy to use. Apparently, since it’s shaped sort of like a gun, you basically just point and shoot, and the analyzer has a screen with the composition. The electrical switches that my family member helps manufacture are used in transmission, distribution and substation applications with power and utility companies, as well as government agencies in the US and abroad. He useD the same XRF analyzer to test my coin that he’d use as part of quality control.
The odds are very high that the actual silver content is 35%. Did you test a number of other war nickels as a control, then if they all were 35% and this one was higher, OK. But I doubt it.
You must understand they Mint more than 1 at a time. In 76 years nothing like you are claiming has ever been reported. It's impossible to have just 1.