There's a lot of stuff that can hurt you, and other stuff that won't. And I'm talking about all chemicals, not just one or two. But there's also a great many variables involved. Even stuff that just about everybody has under the sink, if some of it was mixed together it could cause a heckuva explosion or produce a deadly gas - but used as directed it's not gonna hurt ya. With chemicals, specifics define everything, and I'm not qualified to advise on that. But there are several chemists who are members here, one is even a chemistry professor. So if you want specifics, ask them - Kentucky and Desertgem - and there's a couple more besides them.
Chief among these is the combination of any acid-containing toilet bowl cleaner and any chlorine bleach product. That is the beginning of one of your worst days. After you struggle to your feet (if you can), you need to ventilate thoroughly. There is a pitched debate over whether Thiourea is or is not a carcinogen. My personal view is that it is not, but people of good faith disagree on that.
E-Zest (formerly Jeweluster) is commonly available at retail, and the specific product most are referring to when discussing "dip" as a verb. It's 5% thiourea and 2% sulfuric acid by weight. LD50 is guesstimated at ~2g/kg orally. Which is to say, I'd need to drink about 4 containers of it at one sitting to kill myself. As long as one practices elementary safety precautions - don't use it as creamer, don't hyperventilate with one's nose three-quarters of an inch from the open container, use something else as shampoo - its' use is relatively benign. The whole point of it is, the moment its' use is done you're rinsing the bejeezus out of everything that came into contact with it anyways, as the proper procedure for getting what you desire from it.
Here's an example: I'm using EZ-est near my kitchen sink so when I am done with the dip of the particular coin, I can have my first rinse stage be a minute blast of tap water. I finish dipping and I am in clean up mode. I then scrub the heck out of my kitchen sink to make sure any plate that later gets put in the sink isn't contaminated. I realize this opens me up to--you shouldn't rinse in kitchen sink, but I'm wondering if this is the degree of caution most would use in this sort of setup or is it overkill or is it blindly irresponsible, etc...
BTW, the "acid" in your (and your cat's) stomach is sulfuric acid...ever see what they do after they heave?
Actually stomach acid, or gastric acid, is composed of mostly hydrochloric acid with some potassium chloride and sodium chloride. There is no sulfuric acid. Although you mught think there is if you burp after eating a hard boiled egg.
Oops...sorry, I usually use the example of hydrochloric in your stomach and sulfuric in your car battery...senior moment.
I HAVE A ISRAELI "JONAH THE WHALE" SILVER PROOF COIN THAT I HAVE RECENTLY NOTICED SMUDGES ON ! ANY ADVICE ON REMOVING THEM? THIS IS A EXPENSIVE COIN ONLY 2800 MINTED, DON'T WANT TO RUIN IT! I HAVE SOME VERDI-CARE, WOULD THAT HELP? THANKS FOR ANY ADVICE.
You should start new thread with pics. You're question will not get good attn buried deep in this thread
Simple answer - no. Now you can start a new thread and post pictures if you wish but the bottom line is this - you should not even attempt to do anything yourself. The very fact that you ask that question tells me that you, and I mean no offense by this, do not know what you are doing. And that means you should not even try. I don't know if your coin can even be helped, and posting pictures may or may not allow someone else to determine if it can be helped. But even if it can be you should not be the one to do it. Your only real choice would be to send the coin in to either NGC or PCGS or ICG and let them determine if they can clean the coin.
I like to "swirl" my coins in the stuff. That means either being very gentle so you don't mark up the "face down side" or even drop a patch of fabric from an old flannel shirt in the bottom of the dish. I use a glass dish. I also will farther dilute my stock solution in order to slow down the reaction, if my aim is to reduce, rather than kill, the toning. As you use the stuff, tiny flecks of pure sulfur will begin to precipitate in the liquid. When it gets to the point you can smell it, use fresh juice. This is a formula adapted from one from Eastman Kodak Company, intended to rescue textile items stained with silver sulfides from darkroom use. Towels, your new best white dress shirt that your wife just got you, you know the drill. The unused stuff is pretty stable. It doesn't "go bad" if in a tightly closed container.
Hey when the stuff turns blue-ish is it possible that copper sulfide (or whatever the blue stuff is) is being redeposited on subsequent coins?
Hmm. I don't recommend this at all for copper. It's for silver only. But if you use it for copper, the answer is "yes". If and when the pH of the solution goes alkaline, even when considering silver, this WILL deposit toning ONTO silver coins. {Hint, hint.}
Right...I am getting a little paranoid about reusing it at all. But it seems so wasteful to use a new batch for each coin. That is probably best though, huh?
Oh, no, no, no. You can do maybe 25 coins with one batch, depending on how much toning you remove. As long as the yellow sulfur precipitate doesn't create the rotten eggs smell, you're good. And if you see toning going ON a coin, just add a little citric acid powder to lower the pH.