Let's remove some verdigris, shall we?

Discussion in 'World Coins' started by SuperDave, Feb 8, 2017.

  1. ValpoBeginner

    ValpoBeginner Well Known Supporter

    Much better picture of the verdigris we are trying to remove. 20170212_230455_Richtone(HDR)-01.jpeg
     
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  3. ValpoBeginner

    ValpoBeginner Well Known Supporter

    Ok ran it three cycles in the shot glass within the ultrasonic bath. It did remove the verdigris, but had some unintended consequences. Here are the pics of after using sodium hydroxide to dissolve verdigris.

    20170212_232734_Richtone(HDR)-02-01.jpeg

    Obverse looks better huh. No damage to the carbon or more importantly the copper.
    20170212_232638_Richtone(HDR)-01-02.jpeg

    This is where things went too far.. That hole appeared where the verdigris was, and exposed this hole. Also it appears that some AT occurred at the upper left leaves. This I am sure is due to the temperature of the water. Somewhere betwern 120 and 140.

    I think I'll just buy the aforementioned Verdi-gone for my large cents and I know I'll have to be cateful in exposing holes where the copper oxidized.

    All in all not a bad experiment. I learned that although some things that are supposed to work in theory can use some finesse and genuine expertise. Had fun trying though. Good night.
     
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  4. ValpoBeginner

    ValpoBeginner Well Known Supporter

    Looking forward to SuperDaves results.
     
  5. Paul M.

    Paul M. Well-Known Member

    That is a really impressive performance for VerdiCare.

    Acetone is totally safe as long as you are careful about open flames, and you're not made of styrofoam. :p Basically, don't chug it or huff it, and you'll be fine handling small quantities. There's a reason it's the main component of fingernail polish remover.

    I have a rose bush literally outside my door. :)
     
  6. ValpoBeginner

    ValpoBeginner Well Known Supporter

    What Materials on a coin's surface would acetone take care of?
     
  7. ValpoBeginner

    ValpoBeginner Well Known Supporter

    I need something for carbon spots. Anything for that? It has to be almost impossible to attain because we are carbon based right. Probably would damage the coin's lustre too and turn it strange colors.
     
  8. ValpoBeginner

    ValpoBeginner Well Known Supporter

    I don't have the facilities to work with HYDROCHLORIC acid or aqua regia. I can handle a little Lye (mild strength base) , but when it comes to acids I need a real lab.
     
  9. Bill in Burl

    Bill in Burl Collector

    I've found that, working with large cents, if the vertigris is hard or compacted that you can get it off with a combination of thorns and chemicals. However, once you get the hard stuff off, you will find that there is a hole/pit/depression where the metal has physically corroded into the copper. Many times, when I get the hard green crap, I just leave it like it is, because that is less noticeable than the black hole/pit that it leaves. The soft green oily stuff from pvc comes off easily with acetone.
     
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  10. GDJMSP

    GDJMSP Numismatist Moderator

    There's been thread after thread written on the subject so I'll try and keep it short. Acetone will only work on a few things: PVC residue, tapes and adhesives, some glues (not others). Some, stress some, oily substances; I say that because acetone doesn't work very well on oil per se, but some oily like substances, it'll take it off. (Xylene works much better on oils). And some organic compounds, but with most of those just about any liquid would take them off.


    Good luck with that ! And there's a reason I say that, namely that most of the spots that people "call" carbon spots, are not carbon spots at all. But dark, or black colored spots caused by something else entirely, usually organic in nature. Carbon spots, real carbon spots, are for all practical purposes impossible to remove. That's because they are embedded into the metal itself, they are an impurity within the metal, not something "on" the metal. Things "on" the metal can usually be removed. Things "in" the metal cannot.
     
  11. Insider

    Insider Talent on loan from...

    Except on gold.
     
  12. GDJMSP

    GDJMSP Numismatist Moderator

    If you can remove them, (without damaging the coin) even on gold, then I'd be pretty well convinced they were not real carbon spots.

    But hey, I'd let ya show me ;)
     
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  13. Insider

    Insider Talent on loan from...

    I need to correct my post: :facepalm::eggface: carbon spots on copper are black; that's why they call them carbon spots.

    The spots on gold that I said were easy to remove are called copper spots.


    The person who discovers how to remove them from cents without a trace will end up richer than Midas!
     
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  14. SuperDave

    SuperDave Free the Cartwheels!

    First round of work with the Verdi-Care. I shot this quick and dirty, without much attention to "presentation" appearance (the detail pics are merely 100% crops of the first image, which is forced to half-size for posting here):

    VDCareRound1full.JPG

    VDCareRound1fulldetail1.JPG

    VDCareRound1fulldetail2.JPG

    VDCareRound1fulldetail3.JPG

    VDCareRound1fulldetail4.JPG

    First takeaway - Verdi-Care works. I did very little mechanical work, a little with hawthorn (every bit as tough and sharp as Bill said), and a little with Q-tips. Half an hour's contact with the stuff, total, and there's nothing left on the coin I'd characterize as "green" any longer. This has isolated the places which do need detailed attention, and that's the next step.

    At this point, I don't believe this coin is a candidate for "complete removal." We'll get most of it, and preserve it for the future, but there are a couple places I think the damage is permanent.
     
  15. Insider

    Insider Talent on loan from...

    Someone please PM SuperDave and tell him he needs to keep his day job! :hilarious::hilarious::hilarious: Let him know that I will help him out if he takes me off "IGNORE" and PM's me. I have a very big heart :angelic: and don't wish to see coins mistreated.

    VerdiCare is probably a great preservative (I bought a bottle and have used it); however, that coin is not even halfway done. I know, I know, first round; :rolleyes: but I cannot wait a month to see the results. :yawn:

    Somewhere on CT, I've read about a much better corrosion remover (used at NCS) that in less than a minute does a better job and gets the coin ready for a final application of VC if you don't choose another common product - Coin Care.

    Earlier I posted that the coin was corroded. At this time there is no way to remove the brown spot damage to the surface that remains after the coin was treated. :(
     
    Last edited: Feb 13, 2017
  16. GDJMSP

    GDJMSP Numismatist Moderator

    I hope you're merely commenting about that product, as opposed to actually recommending it. I say that because Coin Care leaves an oily film on coins. And that's not a good thing !

    And there never will be. That is because in order for verdigris to even be formed on a coin some of the metal of the coin has to be literally consumed, eaten away, by corrosion. And naturally, if some of the metal is eaten away then the coin is permanently damaged.

    Now I'm not familiar with this other product (corrosion remover) you're mentioning so I cannot speak as to its effectiveness. But I am familiar with Verdi-Care, and it does its job quite well. What that job is exactly, is to remove the verdigris without causing further damage to the coin. But Verdi-Care cannot and will not repair the damage already done by the corrosion.

    You obviously already know that, but there's a whole lot of other people who don't, which is why I am saying it, the way I am saying it. It is important that people realize and understand this. And one more thing - verdigris is the result of corrosion, it is not what causes the corrosion. Verdigris is what the metal of the coin is turned into by the corrosion.
     
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  17. -jeffB

    -jeffB Greshams LEO Supporter

    This is true. Would you also agree that the presence of verdigris can accelerate further corrosion, and that removing it can help prevent further damage?
     
  18. GDJMSP

    GDJMSP Numismatist Moderator

    Yeah, I would, to a limited extent and only under certain conditions.

    Verdigris by its very nature is capable of absorbing moisture, whereas the metal of a coin is not capable of doing so. So, if moisture is present, and that can mean even in the air in the form of humidity, the verdigris can absorb that moisture, hold it against the coin and cause further corrosion.

    However, with proper storage moisture can be limited to a great degree. And if it is then verdigris is, for all practical purposes, a benign substance that will just sit there and cause no further harm. In other words, if a coin has verdigris on it and the coin is properly stored then that verdigris being there isn't going to hurt anything or cause further damage to the coin.

    What I'm trying to say is that verdigris is not the enemy of coins, it is instead merely what the enemies of coins produce on coins. Moisture and contaminants that are in the air are the enemies of coins, all coins. It is these 2 things that cause corrosion on coins.

    So, if you limit both moisture and air flow as much as possible with proper storage then you have done as much as can humanly be done to protect your coins.
     
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  19. Insider

    Insider Talent on loan from...

    I put Coin Care and VerdiCare in the same category...a preservative that is capable of removing (so also a cleaner :facepalm:) some types of stuff on coins too.

    BTW, some forms of oxidation can protect the metal after they form on its surface.
     
  20. -jeffB

    -jeffB Greshams LEO Supporter

    Yep. Otherwise, aluminum would be attacked by water.
     
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  21. GDJMSP

    GDJMSP Numismatist Moderator

    I don't disagree, they are both in the same category - in that regard. However, there is a distinct and I think a very important difference between the two products, a couple of them actually.

    1 - Coin Care leaves an oily film on the the coins, that is not only visible but so visible that it kind of jumps up and slaps you in the face ! Verdi-Care on the other hand also leaves a protective coating on the coins (according to Thad, it's maker). But that coating is all but invisible, and it is not oily. In fact, unless you are the one who put it in the coin, most people would have hard time telling it WAS on the coin.

    2 - Coin Care is often used for what I think of as nefarious purposes. This is because it can simulate, stress simulate, the look of luster that an original chocolate brown and lustrous (real mint luster) copper coin has. And when it is applied by a skilled coin doctor it can sometimes even fool those at the major TPGs. Verdi-Care will not, cannot, do this.
     
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