Perfection or MS/PR-70 is hard to achieve. Without the proper lighting, magnification, and examination technique, tiny imperfections WILL BE MISSED. Additionally, the line between MS/PR-69 is often looser than it might be. One thing that TPGS's might not be as critical as they could be involves spots. At this time, there is no grade guarantee if a spot develops on a coin after it is slabbed. That allows (not saying it happens) for a person to possibly ignore a small spot and still assign a high grade. I treat spots like bag marks because they are detracting. The image below shows some small spots on a Silver Eagle that would eliminate it from "perfection." I just noticed the hit on the "O" and a small imperfection on the "A." If the spots were not present, that little nick makes this coin a "69" in my book. I could understand someone ignoring the tiny mark on the "A." That's because coins are not graded at high power. Unfortunately, that means that all "perfect" coins graded MS/PR-70's are not equal.
@Insider Is it possible for spots to appear on a coin AFTER it has been slabbed? And what would cause that?
Sounds like an opening for someone to start assigning "grades" higher than 70. Maybe one day scanning XRF machines will be cheap and plentiful, and graders will start deducting points based on imperceptible alloy variations across a coin's planchet. Gotta have some reason to keep the coins coming back through.
Happens a lot. Many think the whitish spots on SE are the result of chemical residues left on the planchet. That sounds right to me. I do know that any water vapor in the air gun during slabbing will eventually spot a coin sealed in a slab. Those spots are not like the blobs in the image.
That's probably the most commonly held theory. And it's not just ASEs, the problem occurs on coins from mints worldwide. And they don't all use the same planchet rinses. But there is a problem with that theory. If the milk spots were caused by residues left on the planchet, they could easily be removed by properly dipping the coin. But, dipping does not remove milk spots. That's because dipping can only remove things on the surface of a coin. And since dipping does not remove them, that means the milk spots are not on the surface of the coin, as residues would be. They are within the metal itself. To date, nobody has ever found anything that can safely remove milk spots. For many years PCGS offered a $25,000 reward to anyone who could come up with a way to safely and successfully remove milk spots. Nobody has ever claimed that reward. I agree that can happen and as you say they are not the same. And spots caused by water vapor can easily and safely be removed by dipping the coin.
I would assume that the residue left on the planchet chemically attacked the surface over time, leaving damage that can't be washed away. It's been a while since I've dropped in on those discussions; do we have any XRF analyses or electron-microscope images of the spots? (The former might show foreign materials if they remain, and the latter would show micro-texture changes.)
That is not factual, at all. You have in the past had other suggestions-such as selling the piece, and dipping could make it worse because it is not known if the piece was dipped before, and it is not known if PVC contamination was present. I will stick with Halperin: sneezes are worse, followed by nicotine, both permanent destructors.
Most of these spots are not very deep into the SE surface. They can be removed by various methods used to abrade the surface. Some methods the coin doctors use are virtually undetectable unless you are looking for it under magnification! The large stains may be different than the spots. Apparently, they are more difficult to remove so I don't think anyone tries. DON'T ASK!
Roger Burdette has a good section on coppper spotting on Saints/gold coins in his SAINT-GAUDENS book.
How the hell are water vapor, sneezes, and nicotine hitting a coin ? People are smoking while looking at raw coins ?
Yes, they can appear after slabbing, even many years after slabbing. I had the 2011 Anniversary set with all 5 coins in PR70/MS70. They were stable up until about 2018, then they started spotting, one by one until all had spots. They were kept in a dry, controlled environment and I think all it did was postpone the inevitable. I got rid of all my "special set" and proof ASEs after that and don't purchase them anymore, unless for a flip.