I like Cleaned Coins and you should to thread

Discussion in 'Coin Chat' started by mrbrklyn, Apr 29, 2012.

  1. Kentucky

    Kentucky Supporter! Supporter

    OK, math time, someone check me:
    Silver dollar diameter = 38.1mm = 3.81cm
    Radius = 1.905cm
    Face Area = pr[SUP]2[/SUP] = 11.40 cm[SUP]2[/SUP] X 2 for 2 sides = 22.80 cm[SUP]2[/SUP]
    Circumference = pd = 11.97 cm
    Thickness = 2.58 mm = 0.258 cm
    Area of edge = 11.97 cm X 0.258 cm = 3.09 cm[SUP]2[/SUP]
    Total area = 25.89 cm[SUP]2[/SUP]
    Thickness of an Ag atom = 144 pm = 144 X 10[SUP]-12[/SUP] m = 144 X 10[SUP]-10[/SUP] cm = 1.44 X 10[SUP]-8[/SUP] cm
    Assume we go 100 atoms deep for 1.44 X 10[SUP]-6[/SUP] cm
    So: (1.44 X 10[SUP]-6[/SUP] cm)( 25.89 cm[SUP]2[/SUP]) = 0.000037 cm[SUP]3[/SUP]
    At a density of 10.49 g/ cm[SUP]3[/SUP] this would be 0.0004 g
    Measureable, but just barely so, and this is removing 100 atoms uniformly and assuming they are all touching.
     
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  3. areich

    areich America*s Darling

    Toning will be visible if you cut in half and your math is likely wrong, not that I have much experience in these matters.
     
  4. Kentucky

    Kentucky Supporter! Supporter

    Your math is likely wrong? Your math is likely wrong! You can't just say that, prove it or I can just say that you are likely wrong also. (not being mad, just stirring the pot)
     
  5. Kentucky

    Kentucky Supporter! Supporter

    Toning/Corrosion/Cleaning experiment

    I thought it would be interesting to take some moderately new cents (shiny ones) and subject them to a variety of treatments: 1) letting water evaporate from the coin repeatedly
    2) letting distilled water evaporate from the coin repeatedly
    3) letting acetone evaporate from the coin repeatedly
    4) letting xylene evaporate from the coin repeatedly

    What do you think? Suggestions
     
  6. GDJMSP

    GDJMSP Numismatist Moderator

    I think you'll learn a few things is what I think. But in order for your experiments to have validity you'll have to follow the same specific process each time. Two things are of vital importance. 1 - each coin must be rinsed at least 3 times in clean liquid to make sure there are no contaminants in solution in the liquid. 2 - the coins have to be stood on edge on a towel or soft absorbent cloth to dry.

    Number 2 will accomplish two things for you. It will allow any excess moisture to run off the coin so it does not pool in low areas like it would if the coin were laying down flat. And it will allow both sides of the coin to be exposed to the air for proper drying.
     
  7. Hunt1

    Hunt1 Active Member

    It looks copy and pasted to be honest lol
     
  8. Kentucky

    Kentucky Supporter! Supporter

    You are absolutely right, I did it in Word and copied and pasted it. Much easier to do superscripting and subscripting that way.
     
  9. mrbrklyn

    mrbrklyn New Member

    The galvametric properties of silver would make your assertion impossible. When you look at the Nerst Equations and Voltage potential for silver there is NO WAY your only going to get a few microns of toning.
     
  10. mrbrklyn

    mrbrklyn New Member

    Metal Potential, Volts Metal Potential, Volts
    Calcium +2.20 Hydrogen 0.000
    Magnesium +1.87 Antimony -0.190
    Aluminum +1.30 Arsenic -0.320
    Manganese +1.07 Bismuth -0.330
    Zinc +0.758 Copper -0.345
    Chromium +0.600 Mercury -0.799
    Iron +0.441 Silver -0.800
    Cadmium +0.398 Platinum -0.863
    Nickel +0.220 Gold -1.100
     
  11. mrbrklyn

    mrbrklyn New Member

  12. mrbrklyn

    mrbrklyn New Member

  13. Kentucky

    Kentucky Supporter! Supporter

    Heavy

    I'm not sure what this has to do with film thickness, but don't get so complicated. Try this instead

    table.jpg
    The metals are ranked in order of being reactive from most to least (nickel should be below iron and above tin).
    Interesting in that it shows nickel should be reactive while silver is one of the least reactive. Enough chemistry!
     
  14. Kentucky

    Kentucky Supporter! Supporter

    Micron = micrometer = 1.0 X 10[SUP]-6[/SUP]m

    So, I said 1.44 X 10[SUP]-6[/SUP]cm which is 1.44 X 10[SUP]-8[/SUP]m while the linked article (which actually talks about coins) says 1.0 X 10[SUP]-7[/SUP]m to 5.3 X 10[SUP]-7[/SUP]m, so I appear to be off by an order of magnitude and the max weight loss with equal depth toning over the entire surface of the coin might reach 0.004 g. Interesting article BTW.

    http://www.jhonecash.com/research/toning_physics.asp
     
  15. Kentucky

    Kentucky Supporter! Supporter

    One other thing I noticed from the "Reactivity Series of Metals" chart is how reactive Aluminum is. The reason we can make aluminum coins is that the aluminum metal immediately forms a continuous protective coating of oxide so we really don't have an aluminum surface, but an aluminum oxide surface.
     
  16. areich

    areich America*s Darling

    why silver batteries then?
     
  17. mrbrklyn

    mrbrklyn New Member

    which is why it is anodized.
     
  18. ska69

    ska69 Member

    I'm sorry, but if water or a bit of rubbing alcohol destroys a coin then I don't want it in my collection to begin with. If a coin is that extremely rare and fragile, as a responsible collector, it shouldn't be in my collection either. It should be in a museum where it will be properly preserved.
     
  19. Kentucky

    Kentucky Supporter! Supporter

    Because the Hunt brothers were trying to collect them....what does this have to do with anything????
     
  20. Kentucky

    Kentucky Supporter! Supporter

    Anodizing = surface oxidation
     
  21. mrbrklyn

    mrbrklyn New Member

    Which of your coins is anodized?
     
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