I followed a similar discussion on a German board between chemists
( I am a chemical engineer so I could follow the discussion somewhat )
PVC is a plastic(polyvinylchloride) like PE ( polyethylene ) and PP
( Polypropylene ) and ABS ( Acrylobutadienestyrene ) and PS
( polystyrene ) etc .....
PVC gets brittle with age and therefore a product was added called plasticiser which kind of oils the PVC but which can leach out and attack especially silver ( do not ask me why ) and therefore the concensus was to dip any new acquired coin in acetone ( this will remove the plasticiser)
Some people also claimed that some of the chlorine could attack copper and give copperchoride which is green rot on coins
So you want a flip or plastic without plasticiser and I guess preferably without chlorine
At the bottom of attached link you will find a lot of other plastics
I think 2X2 holders are Mylar and airtites and the like are acrylics
I do not know what present day flips are made off but I am sure they left the plasticiser out at least
http://www.psrc.usm.edu/macrog/pvc.htm
You can read a lot about coinholders at following site
http://rg.ancients.info/guide/holders.html